MILLER-STEPHENSON CHEMICAL CO INC. -- MS-170/CO2;1,1,1-TRICHLOROETHANE  -- 6810-01-079-1851
<pre>=====================  Product Identification  =====================

Product ID:MS-170/CO2;1,1,1-TRICHLOROETHANE
MSDS Date:12/01/1993
FSC:6810
NIIN:01-079-1851
MSDS Number: BWFPD
=== Responsible Party ===
Company Name:MILLER-STEPHENSON CHEMICAL CO INC.
Address:GEORGE WASHINGTON HIGHWAY
Box:950
City:DANBURY
State:CT
ZIP:06810
Country:US
Info Phone Num:203-743-4447
Emergency Phone Num:203-797-2212 OR 800-424-9300
Preparer's Name:JANET STEPHENS
CAGE:18598
=== Contractor Identification ===
Company Name:MILLER-STEPHENSON CHEMICAL CO INC
Address:55 BACKUS AVE/GEORGE WASHINGTON HWY
Box:950
City:DANBURY
State:CT
ZIP:06810
Country:US
Phone:203-743-4447
CAGE:18598

=============  Composition/Information on Ingredients  =============

Ingred Name:METHYL CHLOROFORM (1,1,1-TRICHLOROEHANE)  (SARA III)
CAS:71-55-6
RTECS #:KJ2975000
Fraction by Wt: 98.6%
Other REC Limits:NONE RECOMMENDED
OSHA PEL:350 PPM
ACGIH TLV:350 PPM/450STEL;9394
EPA Rpt Qty:1000 LBS
DOT Rpt Qty:1000 LBS
Ozone Depleting Chemical:1

Ingred Name:CARBON DIOXIDE
CAS:124-38-9
RTECS #:FF6400000
Fraction by Wt: 3.2%
Other REC Limits:NONE RECOMMENDED
OSHA PEL:5000 PPM
ACGIH TLV:5000PPM/30000STEL;94

=====================  Hazards Identification  =====================

LD50 LC50 Mixture:ORAL LD50 (RAT) IS 9600 MG/KG (INGRED 1)
Routes of Entry: Inhalation:YES  Skin:YES  Ingestion:YES
Reports of Carcinogenicity:NTP:NO    IARC:NO	OSHA:NO
Health Hazards Acute and Chronic:**POISON** EYES:MAY CAUSE EXTREME
    IRRITATION.SKIN:MAY CAUSE IRRITATION.INGEST:MAY CAUSE GI TRACT
    IRRITATION.MAY CAUSE LUNG DAMAGE IF VOMITED AFTER
    SWALLOWING.INHAL:MAY CAUSE RESPIRATORY IRRITATION.
Explanation of Carcinogenicity:THERE ARE NO INGREDIENTS ABOVE 0.1%
    WHICH ARE IDENTIFIED AS CARCINOGENS BY NTP,IARC OR OSHA.
Effects of Overexposure:INCOORDINATION AND IMPAIRED JUDGMENT MAY OCCUR
    AT VAPOR EXPOSURES FROM 500-1000 PPM. DIZZINESS, DROWSINESS, AND
    GENERAL ANESTETHIC EFFECTS MAY OCCUR IN RANGES OF 1000 PPM AND
    HIGHER.
Medical Cond Aggravated by Exposure:INCREASED SENSITIVITY TO ADRENALIN
    MAY BE CAUSED BY OVER EXPOSURE.

=======================  First Aid Measures  =======================

First Aid:INHALATION: REMOVE TO FRESH AIR. IF NOT BREATHING, GIVE CPR.
    IF BREATHING IS DIFFICULT, GIVE OXYGEN. CALL A PHYSICIAN. EYE:
    FLUSH IMMEDIATELY WITH LARGE AMOUNTS OF WATER FOR 15 MINUTES. GET
    MEDICAL AT TENTION. SKIN: REMOVE CONTAMINATED CLOTHING. WASH WITH
    SOAP AND WATER PROMPTLY. INGESTION: DO NOT INDUCE VOMITING. GIVE
    MILK OR USP MINERAL OIL. GET IMMEDIATE MEDICAL ATTENTION.DO NOT
    GIVE EPINEPHRINE

=====================  Fire Fighting Measures  =====================

Flash Point Method:TOC
Flash Point:NONE
Lower Limits:8
Upper Limits:15
Extinguishing Media:USE WATER FOG, CARBON DIOXIDE, OR DRY CHEMICAL.
Fire Fighting Procedures:WEAR FIRE FIGHTING PROTECTIVE EQUIPMENT AND A
    FULL FACED SELF CONTAINED BREATHING APPARATUS. COOL FIRE EXPOSED
    CONTAINERS WITH WATER SPRAY.
Unusual Fire/Explosion Hazard:CONTAINERS MAY BURST FROM HEAT OF
    FIRE.COMBUSTION OR HEAT OF FIRE MAY PRODUCE HAZARDOUS DECOMPOSITION
    PRODUCTS AND VAPORS.

==================  Accidental Release Measures  ==================

Spill Release Procedures:SMALL SPILL: WIPE UP WITH RAGS OR TOWELS.
    LARGE SPILLS: WEAR NIOSH APPROVED RESPIRATOR. VENTILATE AREA. DIKE
    TO RETAIN FLUID. PUMP UP FREE LIQUID. RESIDUE WILL EVAPORATE
    QUICKLY. DO NOT FLUSH TO SEWER  OR WATERWAY.
Neutralizing Agent:NONE

======================	Handling and Storage  ======================

Handling and Storage Precautions:STORE BELOW 120F IN A DRY,
    WELL-VENTILATED LOCATION, AWAY FROM ANY AREA WHERE THE FIRE HAZARD
    MAY BE ACUTE. KEEP CONTAINERS CLOSED WHEN NOT IN USE.
Other Precautions:DO NOT USE WITH ALUMINUM. READ AND FOLLOW DIRECTIONS
    ON LABEL. DO NOT REUSE CONTAINERS.KEEP AWAY FROM HEAT AND DIRECT
    SUNLIGHT.ROTATE STOCK -- SHELF LIFE=1YEAR.

=============  Exposure Controls/Personal Protection  =============

Respiratory Protection:IN HIGH VAPOR AREA, USE NIOSH/MSHA APPROVED
    RESPIRATOR WITH ORGANIC VAPOR CARTRIDGE. USE SELF-CONTAINED
    BREATHING APPARATUS IF VAPOR LEVELS EXCEED 1000 PPM.
Ventilation:LOCAL EXHAUST RECOMMENDED TO CONTROL VAPORS BELOW 50% OF
    TLV.
Protective Gloves:NEOPRENE, PVA, VITON,POLYETHYLENE GLOVES
Eye Protection:USE CHEMICAL SAFETY GOGGLES.
Other Protective Equipment:APRON AND WORK CLOTHING TO MINIMIZE
    EXPOSURE. EYE WASH STATION & SAFETY SHOWER RECOMMENDED.
Work Hygienic Practices:WASH THOROUGHLY AFTER USE AND BEFORE EATING,
    SMOKING OR USING TOILET FACILITIES. DO NOT BREATH VAPORS OR MIST.
Supplemental Safety and Health
NONE

==================  Physical/Chemical Properties  ==================

HCC:T4
Boiling Pt:B.P. Text:165F,74C
Vapor Pres:120
Vapor Density:4.54
Spec Gravity:1.31
Evaporation Rate &amp; Reference:1.4 CARBON TET=1
Solubility in Water:NEGLIGIBLE
Appearance and Odor:AEROSOL.LIQUID IS CLEAR,COLORLESS WITH ETHEREAL
    ODOR.
Percent Volatiles by Volume:100

=================  Stability and Reactivity Data  =================

Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZING AGENTS
Stability Condition to Avoid:HIGH HEAT, OPEN FLAMES AND OTHER SOURCES
    OF IGNITION
Hazardous Decomposition Products:WHEN INVOLVED IN FIRE,
    1,1,1-TRICHLOROETHANE EMITS HIGHLY TOXIC AND IRRITATING HYDROGEN
    CHLORIDE AND PHOSGENE FUMES.

====================  Disposal Considerations  ====================

Waste Disposal Methods:DISPOSE OF IN ACCORDANCE WITH FEDERAL,STATE AND
    LOCAL REGULATIONS.EPA CODE IS U226.

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