PRESTONE PRODUCTS CORP -- DEICER WASHER FLUID, 2024-138  -- 6850-00N073232
<pre>=====================  Product Identification  =====================

Product ID:DEICER WASHER FLUID, 2024-138
MSDS Date:09/22/1995
FSC:6850
NIIN:00N073232
MSDS Number: CDWTY
=== Responsible Party ===
Company Name:PRESTONE PRODUCTS CORP
Address:39 OLD RIDGEBURY RD
City:DANBURY
State:CT
ZIP:06810-5109
Country:US
Info Phone Num:203-830-7800
Emergency Phone Num:800-424-9300(CHEMTREC)
Preparer's Name:JAMES OTTOWITZ
CAGE:EO340
=== Contractor Identification ===
Company Name:PRESTONE PRODUCTS CORPORATION
Address:55 FEDERAL ROAD
City:DANBURY
State:CT
ZIP:06810
Country:US
Phone:203-830-7865
CAGE:EO340

=============  Composition/Information on Ingredients  =============

Ingred Name:METHANOL; (METHYL ALCOHOL) (SARA 313) (CERCLA) LEL: 3.2% 
    LD50 (ORAL, RAT): 9100 MG/KG
CAS:67-56-1
RTECS #:PC1400000
Fraction by Wt: 30-40%
OSHA PEL:S, 200 PPM
ACGIH TLV:S,200PPM/250STEL; 95
EPA Rpt Qty:5000 LBS
DOT Rpt Qty:5000 LBS

Ingred Name:ETHYLENE GLYCOL (SARA 313) (CERCLA) UEL: 36% LD50 (ORAL,
    RAT): 4700 MG/KG
CAS:107-21-1
RTECS #:KW2975000
Fraction by Wt: 1-10%
OSHA PEL:N/K 
ACGIH TLV:C 50 PPM,VAPOR; 9495
EPA Rpt Qty:1 LB
DOT Rpt Qty:1 LB

Ingred Name:NON-HAZARDOUS INGREDIENTS
Fraction by Wt: >1%
OSHA PEL:N/K 
ACGIH TLV:N/K 

Ingred Name:WATER
CAS:7732-18-5
RTECS #:ZC0110000
Fraction by Wt: 50-70%
OSHA PEL:N/K 
ACGIH TLV:N/K 

Ingred Name:EFTS OF OVEREXP:PERCEPTION, REDUCTION OF VISUAL FIELDS &
    COMPLETE BLND. W/MASSIVE OVERDOSE, LIVER, (ING 6)
RTECS #:9999999ZZ

Ingred Name:ING 5:KIDNEY & HEART MUSCLE INJURY HAVE BEEN DESCRIBED.
    THERE MAY BE A DELAY OF SEVERAL HRS BTWN SWALLOWING (ING 7)
RTECS #:9999999ZZ

Ingred Name:ING 6:METHANOL & THE ONSET OF SYMPS. SEV KIDNEY DMG FOLLOWS
    THE INGEST OF LRG VOL OF ETHYLENE GLYCOL. CHRONIC: (ING 8)
RTECS #:9999999ZZ

Ingred Name:ING 7:LONG TERM RPTD OVEREXP TO METHANOL VAP CONCS OF 3000
    PPM GREATER MAY ALLOW A (ING 9)
RTECS #:9999999ZZ

Ingred Name:ING 8:CUMULATIVE EFT TO OCCUR W/RSLT NAUS, VOMIT, HDCH,
    RINGING IN THE EARS, INSOMNIA, TREMBLING, UNSTEADY (ING 10)
RTECS #:9999999ZZ

Ingred Name:ING 9:GAIT, VERTIGO, & CLOUDED & DOUBLE VISION. PRLNG
    OVEREXP AT LEVELS OF 800 TO 100 PPM MAY RSLT IN SEVERE (ING 11)
RTECS #:9999999ZZ

Ingred Name:ING 10:EYE DMG IN SOME PERS. COMPONENTS OF THIS PROD ARE
    NOT SUSPECTED CARCIN. SIGNIFICANT LAB DATA W/POSS (ING 12)
RTECS #:9999999ZZ

Ingred Name:ING 11:RELEVENCE TO HUMAN HLTH HAZS:ANIMAL STUDIES SUGGEST
    THAT ETHYLENE GLYCOL AT HIGH DOSES CAN PRDCE BIRTH DEFECTS.
RTECS #:9999999ZZ

Ingred Name:FIRST AID PROC:IF IRRITAT, PAIN, SWELL/TEARING PERSISTS,
    SEEK IMMED MED ATTN. INGEST:GIVE ONE/TWO GLASSES OF (ING 14)
RTECS #:9999999ZZ

Ingred Name:ING 13:H*2O & INDUCE VOMIT. NEVER GIVE ANYTHING BY MOUTH TO
    AN UNCON PERS. IMMED CALL MD, POIS CTL CTR EMER (ING 15)
RTECS #:9999999ZZ

Ingred Name:ING 14:ROOM FOR ASSISTANCE & INSTRUCTIONS ON INDUCING VOMIT
    & OTHER EMER FIRST AID TREATMENT. NOTES TO MD: (ING 16)
RTECS #:9999999ZZ

Ingred Name:ING 15:COMBINATION OF VISUAL DISTURBANCE, METABOLIC
    ACIDOSIS & FORMIC ACID IN THE URINE IS EVIDENCE OF METHANOL(ING 17)
RTECS #:9999999ZZ

Ingred Name:ING 16:POISONING. THE PRINCIPAL TOX EFTS OF ETHYLENE GLYCOL
    WHEN INGESTED, ARE KIDNEY DMG & METABOLIC ACIDOSIS.(ING 18)
RTECS #:9999999ZZ

Ingred Name:ING 17:ETHANOL IS ANTIDOTAL, & ITS EARLY ADMIN MAY BLOCK
    THE FORMATION OF TOX METABOLITES OF BOTH METHANOL & (ING 19)
RTECS #:9999999ZZ

Ingred Name:ING 18:ETHYLENE GLYCOL. HEMODIALYSIS IS HIGHLY EFFECTIVE AT
    REMOVING METHANOL, ETHYLENE GLYCOL & THEIR (ING 20)
RTECS #:9999999ZZ

Ingred Name:ING 19:METABOLITIES, AND MAY BE INDICATED DEPENDING UPON
    THE CLINICAL SITUATION OF BLOOD LEVELS.
RTECS #:9999999ZZ

Ingred Name:RESP PROT:FOUND IN THE WORK PLACE, MUST BE BASED ON
    SPECIFIC OPERATION, MUST NOT EXCEED THE WORKING LIMITS OF (ING 22)
RTECS #:9999999ZZ

Ingred Name:ING 21:(NIOSH). A SUPPLIED AIR RESPIR W/FULL FACEPIECE
    OPERATED IN CONTINUOUS FLOW MODE. POSITIVE PRESS SCBA. (ING 23)
RTECS #:9999999ZZ

Ingred Name:ING 22:ORGANIC VAP CARTRIDGE RESPS ARE NOT REC FOR METHANOL
    VAP EXPOS. FORE FIREFIGHTING & OTHER IMMED DANGEROUS(ING 24)
RTECS #:9999999ZZ

Ingred Name:ING 23:TO LIFE OR HEALTH CONDITIONS INCLUDING ALL
    SITUATIONS OF UNKNOWN CONTAMINANT FACEPIECE & IS OPERATED IN (ING
    25)
RTECS #:9999999ZZ

Ingred Name:ING 24:PRESSURE-DEMAND OR OTHER POSITIVE PRESSURE MODE.
RTECS #:9999999ZZ

=====================  Hazards Identification  =====================

LD50 LC50 Mixture:SEE INGREDIENTS
Routes of Entry: Inhalation:YES  Skin:YES  Ingestion:YES
Reports of Carcinogenicity:NTP:NO    IARC:NO	OSHA:NO
Health Hazards Acute and Chronic:EMER OVERVIEW: FLAMM LIQ! EYE IRRIT.
    INHAL MAY CAUSE HDCH, DIZZ, DROWS, NAUS, VISUAL IMPAIRMENT, NARCOS
    & UNCONSCIOUSNESS. POISONOUS IF SWALLOWED. ACUTE:NO ACUTE TOX ETS
    EXPECTED WHEN PROD IS USED AS  DIRECTED. INHAL:INHAL OF HIGH CONC,
    PARTICULARLY MISTS, MAY CAUSE IRRIT OF THE NOSE & THROAT W/HDCH,
    (EFTS OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT.
Effects of Overexposure:HLTH HAZ:DIZZ, DROW, & DISTURB OF VISION.
    SKIN:PRLNG CNTCT W/SKIN TO METHANOL MAY CAUSE REDDENING & DEFAT OF
    THE SKIN. METHANOL MAY BE ABSORBED THRU THE SKIN POSSIBLY RSLTG IN
    HARMFUL EFTS. EYE:MAY BE  IRRITG & CAUSE PAIN, TEARING, REDDENING &
    SWELL ACCOMPANIED BY THE STINGING SENSATION &/FEELING LIKE THAT OF
    (SUPDAT)
Medical Cond Aggravated by Exposure:DUE TO ITS DEFATTING PROPERTIES,
    METHANOL MAY AGGRAVATE AN EXISTING SKIN CONDITION.

=======================  First Aid Measures  =======================

First Aid:INHAL:IF SYMPS OF EXPOS DEVELOP, REMOVE TO FRESH AIR. IF
    BRTHG BECOMES DFCLT, ADMINISTER OXYGEN IF AVAIL. ADMINISTER ARTF
    RESP IF BRTHG STOPS. SEEK IMMED MED ATTN. SKIN:REMOVE CONTAMD
    CLTHG. FLUSH EXP OSED SKIN W/COPIOUS AMTS OF H*2O & WASHW/SOAP. IF
    IRRIT DEVELOPS & PERSISTS, SEEK MED ATTN. EYE:EXPOSED EYES SHOULD
    BE REMOVED WHILE FLUSHING. FLUSH FOR A MIN OF 15 MIN/UNTIL IRRIT
    SUBSIDES. (ING 13)

=====================  Fire Fighting Measures  =====================

Flash Point Method:SCC
Flash Point:90.0F,32.2C
Lower Limits:SEE INGS
Upper Limits:SEE INGS
Extinguishing Media:USE WATER FOG, CARBON DIOXIDE, ALCOHOL FOAM OR DRY
    CHEMICAL. COOL FIRE EXPOSED CONTAINERS WITH WATER.
Fire Fighting Procedures:USE NIOSH APPROVED SCBA & FULL PROTECTIVE
    EQUIPMENT .
Unusual Fire/Explosion Hazard:FLAMM LIQ. METHANOL-WATER MIX WILL BURN
    UNLESS VERY DILUTE. FLAME IS INVISIBLE IN DAYLIGHT. VAPS ARE
    HVR/AIR & MAY FLOW ALONG SURF TO DISTANT IGNIT (SUPDAT)

==================  Accidental Release Measures  ==================

Spill Release Procedures:ELIMINATE ALL IGNITION SOURCES. VENTILATE
    AREA. WEAR APPROPRIATE PROTECTIVE CLOTHING AND EQUIPMENT. COLLECT
    WITH ABSORBENT MATERIAL AND PLACE IN APPROPRIATE, LABELED CONTAINER
    FOR DISPOSAL.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

======================	Handling and Storage  ======================

Handling and Storage Precautions:STORE PROD BELOW 120F & AWAY FROM
    DIRECT SUNLIGHT. STORE IN A COOL, WELL VENT AREA. DO NOT SWALLOW.
    AVOID EYE & SKIN CONTACT. AVOID BRTHG VAPS/MISTS.
Other Precautions:USE ONLY WITH ADEQUATE VENTILATION. FLAMMABLE LIQUID!
    KEEP CONTAINER AWAY FROM HEAT, SPARKS, OPEN FLAMES AND ALL OTHER
    SOURCES OF IGNITION. DO NOT SMOKE DURING USE.

=============  Exposure Controls/Personal Protection  =============

Respiratory Protection:THE FOLLOWING RESPS ARE REC ON INFO FOUND IN THE
    PHYSICAL & CHEM PROPERTIES, TOXICOLOGICAL INFO & HLTH HAZS SECTION.
    THEY ARE RANKED IN ORDER FROM MIN TO MAXIMUM RESP PROT. THE
    SPECIFIC RESP MUST BE B ASED ON CONTAM LEVELS (ING 21)
Ventilation:USE GENERAL VENTILATION OR LOCAL EXHAUST AS REQUIRED TO
    MAINTAIN EXPOSURES BELOW THE OCCUPATIONAL EXPOSURE LIMITS.
Protective Gloves:CHEMICAL RESISTANT GLOVES
Eye Protection:ANSI APPROVED CHEM WORKERS GOGGS .
Other Protective Equipment:EYE WASH FOUNTAIN & DELUGE SHOWER WHICH MEET
    ANSI DESIGN CRITERIA .
Work Hygienic Practices:WASH EXPOSED SKIN THOROUGHLY WITH SOAP AND
    WATER AFTER USE.
Supplemental Safety and Health
EXPLO HAZ:SOURCES & FLASH BACK. EFTS OF OVEREXP:FINE DUST IN THE EYES.
    INGEST:MAY CAUSE NAUS, ABDOM PAIN, VOMIT, SHORTNESS OF BRTH,
    FATIGUE & LEG CRAMPS. NERVOUS SYS EFTS INCL:HDCH, CONFUSN, DRUNKEN
    B EHAVIOR, CNS DEPRESS, COMA & DEATH. VISUAL EFTS OF METHANOL INCL
    BLURRED VISION, DOUBLE VISION, CHANGES IN COLOR (ING 5)

==================  Physical/Chemical Properties  ==================

Boiling Pt:B.P. Text:158F,70C
Melt/Freeze Pt:M.P/F.P Text:-32F,-36C
Vapor Pres:36 @ 68F
Vapor Density:>1
Spec Gravity:7.9 LBS/GAL
pH:7.9
Evaporation Rate &amp; Reference:<1 (BUTYL ACETATE=1)
Solubility in Water:100%
Appearance and Odor:CLEAR YELLOW LIQUID WITH SLIGHT ALCOHOL ODOR.
Percent Volatiles by Volume:>95

=================  Stability and Reactivity Data  =================

Stability Indicator/Materials to Avoid:YES
STRONG BASES, STRONG ACIDS, STRONG OXIDIZING AGENTS.
Stability Condition to Avoid:HEAT, SPARKS, FLAMES AND ALL OTHER SOURCES
    OF IGNITION.
Hazardous Decomposition Products:CARBON MONOXIDE, CARBON DIOXIDE.

====================  Disposal Considerations  ====================

Waste Disposal Methods:DISPOSE OF PRODUCT AS HAZARDOUS WASTE
    (IGNITABLE) IN ACCORDANCE WITH ALL LOCAL, STATE/PROVINCIAL AND
    FEDERAL REGULATIONS.

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 of Defense.  The United States of America in no manner whatsoever,
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 disclaims all liability for its use.  Any person utilizing this
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