MONSANTO CO -- ACCORD HERBICIDE  -- 6840-01-356-8892
<pre>=====================  Product Identification  =====================

Product ID:ACCORD HERBICIDE
MSDS Date:08/01/1995
FSC:6840
NIIN:01-356-8892
Status Code:A
MSDS Number: CJSJH
=== Responsible Party ===
Company Name:MONSANTO CO
Address:800 N LINDBERGH BLVD
Box:5008
City:ST LOUIS
State:MO
ZIP:63167
Country:US
Info Phone Num:314-694-6338/800-332-3111
Emergency Phone Num:314-694-4000 (COLLECT)
Resp. Party Other MSDS Num.:S00011151
Preparer's Name:NOT PROVIDED.
CAGE:76541
=== Contractor Identification ===
Company Name:MONSANTO COMPANY
Address:800 N LINDBERGH BLVD
Box:City:SAINT LOUIS
State:MO
ZIP:63167
Country:US
Phone:314-694-6661 OR 800-332-3111
CAGE:76541
Company Name:TIMBERLAND ENTERPRISES INC
Address:140 ARKANSAS ST
Box:557
City:MONTICELLO
State:AR
ZIP:71655
Country:US
Phone:501-367-8561
Contract Num:SP0450-99-M-NG34
CAGE:1HB45

=============  Composition/Information on Ingredients  =============

Ingred Name:ACTIVE INGREDIENT: GLYPHOSATE,N-(PHOSPHONOMETHYL)GLYCINE,IN
    THE FORM OF ITS ISOPROPYLAMINE SALT
CAS:38641-94-0
RTECS #:MC1080000
= Wt:41.5
Other REC Limits:NONE RECOMMENDED

Ingred Name:INERT INGREDIENTS
Fraction by Wt: 58.5%
Other REC Limits:NONE RECOMMENDED

Ingred Name:INERT INGREDIENTS
= Wt:58.5
Other REC Limits:NOT PROVIDED.
OSHA PEL:NOT PROVIDED.
ACGIH TLV:NOT PROVIDED.

=====================  Hazards Identification  =====================

LD50 LC50 Mixture:LD50 (ORAL, RAT) > 5,000 MG/KG
Routes of Entry: Inhalation:YES  Skin:YES  Ingestion:NO
Health Hazards Acute and Chronic:EYE CONTACT: ACCORD HERBICIDE IS NO
    MORE THAN SLIGHTLY IRRITATING BASED ON TOXICIY STUDIES. SKIN
    CONTACT: ACCORD HERBICIDE IS NO MORE THAN SLIGHTLY IRRITATING BASED
    ON TOXICIY STUDIES. INGESTION:: ACC ORD HERBICIDE IS NO MORE THAN
    SLIGHTLY TOXIC BASED ON TOXICIY STUDIES. NO SIGNIFICANT ADVERSE
    HEALTH EFFECTS ARE EXPECTED TO DEVELOP IF ONLY SMALL AMOUNTS (LESS
    THAN A MOUTHFUL) ARE SWALLOWED. INHALAT ION: ACCORD HERBICIDE IS NO
    MORE THAN SLIGHTLY TOXIC IF INHALED BASED ON TOXICIY STUDIES.
Explanation of Carcinogenicity:NOT PROVIDED.
Effects of Overexposure:EYE CONTACT: ACCORD HERBICIDE IS NO MORE THAN
    SLIGHTLY IRRITATING BASED ON TOXICIY STUDIES. SKIN CONTACT: ACCORD
    HERBICIDE IS NO MORE THAN SLIGHTLY IRRITATING BASED ON TOXICIY
    STUDIES. INGESTION:: ACC ORD HERBICIDE IS NO MORE THAN SLIGHTLY
    TOXIC BASED ON TOXICIY STUDIES. NO SIGNIFICANT ADVERSE HEALTH
    EFFECTS ARE EXPECTED TO DEVELOP IF ONLY SMALL AMOUNTS (LESS THAN A
    MOUTHFUL) ARE SWALLOWED. INHALAT ION: ACCORD HERBICIDE IS NO MORE
    THAN SLIGHTLY TOXIC IF INHALED BASED ON TOXICIY STUDIES.
Medical Cond Aggravated by Exposure:NOT PROVIDED.

=======================  First Aid Measures  =======================

First Aid:IF INHALED: REMOVE INDIVIDUAL TO FRESH AIR. SEEK MEDICAL
    ATTENTION IF BREATHING DIFFICULTY DEVELOPS.

=====================  Fire Fighting Measures  =====================

Flash Point Method:TCC
Flash Point:>93.3C, 200.F
Autoignition Temp:Autoignition Temp Text:N/D
Lower Limits:NP
Upper Limits:NP
Extinguishing Media:WATER SPRAY, FOAM, DRY CHEMICAL, CO2, OTHER CLASS B
    EXTINGUISHING AGENT.
Fire Fighting Procedures:FIREFIGHTERS & OTHERS THAT MAY BE EXPOSED TO
    VAPORS/MIST/DUST/PRODUCTS OF COMBUSTION SHOULD WEAR FULL PROTECTIVE
    CLOTHING & SELF-CONTAINED BREATHING APPARATUS. EQUIPMENT SHOULD BE
    THOROUGHLY CLEANED A FTER USE.
Unusual Fire/Explosion Hazard:NONE

==================  Accidental Release Measures  ==================

Spill Release Procedures:OBSERVE ALL PROTECTION AND SAFETY PRECAUTIONS
    WHEN CLAENING UP SPILLS. SMALL SPILLS: (<1GALLON), SOAK UP WITH
    TOWELS AND DISCARD IN TRASH. CLEAN AREA WITH SOAP AND WATER AND
    RINSE THOROUGHLY.  LARGE S PILL: DIKE AND ABSORB WITH BENTONITE OR
    OTHER CLAYS. COLLECT AND PLACE IN A METAL DRUM FOR DISPOSAL.
    THOROUGHLY SCRUB FLOOR WITH A STRONG INDUSTRIAL DETERGENT AND RINSE
    WITH WATER.
Neutralizing Agent:NOT PROVIDED.

======================	Handling and Storage  ======================

Handling and Storage Precautions:STORE ABOVE 10F (12C) TO KEEP FROM
    CRYSTALLIZING. CRYSTALS WILL  SETTLE TO THE BOTTOM. IF ALLOWED TO
    CRYSTALLIZE, PLACE IN WARM ROOM 68F (20C) FOR SEVERAL DAYS TO
    REDISSOLVE AND ROLL OR SHAKE CONTAINE R OR RECIRCULATE IN MINI-BULK
    CONTAINERS TO MIX WELL BEFORE USING.
Other Precautions:DO NOT CONTAMINATE WATER WHEN DISPOSING OF EQUIPMENT
    WASHWATERS. DO NOT CONTAMINATE FOODSTUFFS, FEED OR SEED BY STORAGE
    OR DISPOSAL. KEEP OUT OF REACH OF CHILDREN. CAUT!ION! HARMFUL IF
    INHALED. REFORM ULATION IS PROHIBITED.

=============  Exposure Controls/Personal Protection  =============

Respiratory Protection:AVOID BREATHING MIST OR VAPOR.THIS PRODUCT IS
    NOT LIKELY TO POSE AIRBORNE EXPOSURE CONCERN WHEN HANDLED & USED IN
    ACCORDANCE WITH LABEL INSTRUCTIONS.
Ventilation:NO SPECIAL PRECAUTIONS ARE RECOMMENDED.
Protective Gloves:MINIMIZE SKIN CONTAMINATION BY FOLLOWING GOOD
    HANDLING PRACTICES.
Eye Protection:USE GOOD HANDLING PRACTICES TO AVOID EYE CONTACT.
Other Protective Equipment:APPLICATORS/OTHER HANDLERS MUST WEAR:LONG
    SLEEVED SHIRT, LONG PANTS, AND SHOES W/ITH SOCKS.
Work Hygienic Practices:WASH HANDS AND CONTAMINATED SKIN THOROUGHLY
    AFTER HANDLING.
Supplemental Safety and Health
NONE

==================  Physical/Chemical Properties  ==================

HCC:V5
Boiling Pt:B.P. Text:NOT PROVIDED.
Melt/Freeze Pt:M.P/F.P Text:NP
Decomp Temp:Decomp Text:NP
Vapor Pres:NOT PROVIDED.
Vapor Density:NP
Spec Gravity:1.158
pH:4.6 - 4.8
Viscosity:NOT PROVIDED.
Evaporation Rate &amp; Reference:NOT PROVIDED.
Solubility in Water:NOT PROVIDED.
Appearance and Odor:COLORLESS SOLUTION, ESSENTIALLY ODORLESS
Percent Volatiles by Volume:NP
Corrosion Rate:NP

=================  Stability and Reactivity Data  =================

Stability Indicator/Materials to Avoid:YES
GALVANIZED OR UNLINED STEE; IT MAY FORM HYDROGEN GAS. CAN REACT WITH
    CAUSTIC OR BASIC MATERIALS.
Stability Condition to Avoid:OPEN FLAME,SPARK,WELDER'S TORCH,LIGHTED
    CIGARETTE OR OTHER IGNITION SOURCE.
Hazardous Decomposition Products:NONE KNOWN.

===================  Toxicological Information	===================

Toxicological Information:LD50 (ORAL, RAT) > 5,000 MG/KG; FIFRA
    CATEGORY IV  DERMAL- RABBIT LD50 - > 5000 MG/KG FIFRA CATEGORY IV 
    INHALATION - RAT 4-HR LC50- >1.3 MG/L, THE HIGHEST ATMOSPHERIC
    CONCENTRATION ACHIEVABLE IN THIS  STUDY; FIFRA CATEGORY III   EYE
    IRRITATION - RABBIT (6 ANIMALS), 24-HR OXP.; FIFRA CATEGORY IV 
    SKIN IRRITATION - RABBIT (6 ANIMALS), 24-HR OXP.; FIFRA CATEGORY
    IV.  IN REPEAT DOSING STUDIES (6-MONTH ), DOGS FED MON 0139
    EXHIBITED SLIGHT BODY WEIGHT CHANGES.

=====================  Ecological Information  =====================

Ecological:96-HR LC50 BLUEGILL: >1,000 MG/L- PRACTICALLY NONTOXIC. 
    96-HR LC50 TROUT: >1,000 MG/L- PRACTICALLY NONTOXIC.  48-HR EC50
    DAPHNIA: 930 MG/L- PRACTICALLY NONTOXIC.

====================  Disposal Considerations  ====================

Waste Disposal Methods:WASTE THAT CANNOT BE USED OR CHEMICALLY
    REPROCESSED SHOULD BE DISPOED OF IN A LANDFILL APPROVED FOR
    PESTICIDE DISPOSAL OR IN ACCORDANCE WITH APPLICABLE FEDERAL, STATE
    OR LOCAL PROCEDURES. EMPTY CONTAI NER RETAINS VAPOR AND PRODUCT
    RESIDUE. OBSERVE ALL LABEL SAFEGUARD UNTIL CONTAINER IS CLEANED OR
    DES TROYED. DO NOT REUSE THEM.

===================  MSDS Transport Information  ===================

Transport Information:DOT PROPER SHIPPING NAME, HAZARD CLASS/ID NO,
    LABEL: NOT APPLICABLE.

=====================  Regulatory Information  =====================

SARA Title III Information:NOT APPLICABLE.
Federal Regulatory Information:EPA REG#:524-326. ALL COMPONENTS ARE ON
    THE US EPA'S TSCA INVENTORY LIST.
State Regulatory Information:NOT PROVIDED.

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