SIGMA CHEMICAL CO -- FLUFENAMIC ACID, F9005  -- 6550-00N093189
<pre>=====================  Product Identification  =====================

Product ID:FLUFENAMIC ACID, F9005
MSDS Date:01/01/1999
FSC:6550
NIIN:00N093189
Status Code:A
MSDS Number: CJXPH
=== Responsible Party ===
Company Name:SIGMA CHEMICAL CO
Box:14508
City:ST LOUIS
State:MO
ZIP:63178
Country:US
Info Phone Num:314-771-5765
Emergency Phone Num:314-771-5765
CAGE:21076
=== Contractor Identification ===
Company Name:SIGMA CHEMICAL COMPANY
Address:3050 SPRUCE ST
Box:14508
City:ST LOUIS
State:MO
ZIP:63178
Country:US
Phone:314-771-5765
CAGE:21076

=============  Composition/Information on Ingredients  =============

Ingred Name:ANTHRANILIC ACID, N-(ALPHA, ALPHA,
    ALPHA-TRIFLUORO-M-TOLYL)-; (FLUFENAMIC ACID). LD50:(ORAL,RAT) 249
    MG/KG.
CAS:530-78-9
RTECS #:CB4375000
= Wt:100.

=====================  Hazards Identification  =====================

Routes of Entry: Inhalation:YES  Skin:YES  Ingestion:YES
Reports of Carcinogenicity:NTP:NO    IARC:NO	OSHA:NO
Health Hazards Acute and Chronic:ACUTE: HARMFUL IF SWALLOWED, INHALED
    OR ABSORBED THROUGH SKIN. CAUSES EYE AND SKIN IRRITATION. MAY CAUSE
    CYANOSIS (BLUE-GRAY COLORING OF SKIN AND LIPS CAUSED BY LACK OF
    OXYGEN). EXPOSURE CAN CAUSE: NA RCOTIC EFFECT. TARGET ORGAN DATA:
    BEHAVIORAL (CHANGE IN MOTOR ACTIVITY; ATAXIA; ANTIPSYCHOTIC).
    LUNGS, THORAX OR RESPIRATION (RESPIRATORY DEPRESSION).
    GASTROINTESTINAL (HYPERMOTILITY, DIARRHEA). EFFEC TS ON FERTILITY
    (OTHER MEASURES OF FERTILITY). NUTRITIONAL AND GROSS METABOLIC
    (WEIGHT LOSS OR DECREASED WEIGHT GAIN). TUMORIGENIC (ACTIVE AS
    ANTI-CANCER AGENT).
Effects of Overexposure:SEE HEALTH HAZARDS.

=======================  First Aid Measures  =======================

First Aid:EYES: IMMEDIATELY FLUSH WITH COPIOUS AMOUNTS OF WATER FOR AT
    LEAST 15 MINUTES. SKIN: IMMEDIATELY FLUSH WITH COPIOUS AMOUNTS OF
    WATER FOR AT LEAST 15 MINUTES WHILE REMOVING CONTAMINATED CLOTHING
    AND SH OES. WASH CONTAMINATED CLOTHING BEFORE REUSE. INHALATION:
    REMOVE TO FRESH AIR. IF NOT BREATHING GIVE ARTIFICIAL RESPIRATION.
    IF BREATHING IS DIFFICULT, GIVE OXYGEN. INGESTION: WASH OUT MOUTH
    WITH WATE R PROVIDED PERSON IS CONSCIOUS. CALL MD.

=====================  Fire Fighting Measures  =====================

Extinguishing Media:CARBON DIOXIDE, DRY CHEMICAL POWDER OR APPROPRIATE
    FOAM.
Fire Fighting Procedures:USE NIOSH APPROVED SCBA AND FULL PROTECTIVE
    EQUIPMENT .
Unusual Fire/Explosion Hazard:EMITS TOXIC FUMES UNDER FIRE CONDITIONS.

==================  Accidental Release Measures  ==================

Spill Release Procedures:EVACUATE AREA. WEAR NIOSH APPROVED
    SELF-CONTAINED BREATHING APPARATUS, RUBBER BOOTS AND HEAVY RUBBER
    GLOVES. SWEEP UP, PLACE IN A BAG AND HOLD FOR WASTE DISPOSAL. AVOID
    RAISING DUST. VENTILATE AREA AN D WASH SPILL SITE AFTER MATERIAL
    PICKUP IS COMPLETE.

======================	Handling and Storage  ======================

Handling and Storage Precautions:DO NOT BREATHE DUST. DO NOT GET IN
    EYES, ON SKIN, ON CLOTHING. AVOID PROLONGED OR REPEATED EXPOSURE.
    KEEP TIGHTLY CLOSED. STORE IN A COOL, DRY PLACE.
Other Precautions:TOXIC (U.S.A.). HARMFUL (EU). HARMFUL BY INHALATION,
    IN CONTACT WITH SKIN AND IF SWALLOWED. IRRITATING TO EYES AND SKIN.

=============  Exposure Controls/Personal Protection  =============

Respiratory Protection:WEAR APPROPRIATE NIOSH APPROVED RESPIRATOR.
Ventilation:USE ONLY IN A CHEMICAL FUME HOOD.
Protective Gloves:CHEMICAL-RESISTANT GLOVES.
Eye Protection:ANSI APPROVED CHEMICAL WORKERS GOGGLES .
Other Protective Equipment:EYE WASH AND DELUGE SHOWER MEETING ANSI
    DESIGN CRITERIA . WEAR SUITABLE OTHER PROTECTIVE CLOTHING.
Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING.
Supplemental Safety and Health
MFR'S INFORMATION ON INGREDIENTS: MF: C14H10F3NO2. EC NO: 208-494-1.

==================  Physical/Chemical Properties  ==================

Melt/Freeze Pt:>132.C, 269.6F
M.P/F.P Text:132C TO 135C
Appearance and Odor:WHITE POWDER.

=================  Stability and Reactivity Data  =================

Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZING AGENTS.
Hazardous Decomposition Products:TOXIC FUMES OF: CARBON MONOXIDE,
    CARBON DIOXIDE, NITROGEN OXIDES, HYDROGEN FLUORIDE.

===================  Toxicological Information	===================

Toxicological Information:TO THE BEST OF MFR'S KNOWLEDGE, THE CHEMICAL,
    PHYSICAL AND TOXICOLOGICAL PROPERTIES HAVE NOT BEEN THOROUGHLY
    INVESTIGATED. TOXICITY DATA: LD50:(ORAL,RAT) 249 MG/KG - AIPTAK
    221,132,1976. LD50:(IPR,RAT ) 185 MG/KG; LD50:(ORAL,MUS) 490 MG/KG
    - OYYAA2 16,1011,1978. LD50:(SCU,RAT) 280 MG/KG; LD50:(SCU,MUS) 620
    MG/KG - OYYAA2 18,845,1979. LD50:(IVN,RAT) 98 MG/KG - CMROCX
    4,17,1976. LD50:(IPR,MUS) 150 MG /KG - NTIS** AD691-490.
    LD50:(IVN,MUS) 158 MG/KG - YKKZAJ 89,1392,1969. LD50:(IMS,MUS) 500
    MG/KG - PCJOAU 17,353,1983. LD50:(ORAL,GPG) 925 MG/KG - PHMGBN
    11,220,1974. ONLY SELECTED REGISTRY OF TOXIC E FFECTS OF CHEMICAL
    (OTHER INFO)

=====================  Ecological Information  =====================

Ecological:DATA NOT YET AVAILABLE.

====================  Disposal Considerations  ====================

Waste Disposal Methods:DISSOLVE OR MIX THE MATERIAL WITH A COMBUSTIBLE
    SOLVENT AND BURN IN A CHEMICAL INCINERATOR EQUIPPED WITH AN
    AFTERBURNER AND SCRUBBER. OBSERVE ALL FEDERAL, STATE AND LOCAL
    ENVIRONMENTAL REGULATIONS.

===================  MSDS Transport Information  ===================

Transport Information:CONTACT SIGMA CHEMICAL COMPANY FOR TRANSPORTATION
    INFORMATION.

=====================  Regulatory Information  =====================

Federal Regulatory Information:EUROPEAN INFORMATION: HARMFUL; R
    20/21/22 - HARMFUL BY INHALATION, IN CONTACT WITH SKIN AND IF
    SWALLOWED. R 36/38 - IRRITATING TO EYES AND SKIN. S 26 - IN CASE OF
    CONTACT WITH EYES, RINSE IMMEDIATELY  WITH PLENTY OF WATER AND SEEK
    MEDICAL ADVICE. S 36 - WEAR SUITABLE PROTECTIVE CLOTHING.

=======================  Other Information  =======================

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