Carminic Acid
MSDS Number: C1386 --- Effective Date: 12/08/96
1. Product Identification
Synonyms: C.I. Natural Red 4; C.I. 75470
CAS No.: 1260-17-9
Molecular Weight: 492.4
Chemical Formula: C22H20O13
Product Codes: E379
2. Composition/Information on Ingredients
Ingredient CAS No Percent Hazardous
--------------------------------------- ------------ ------- ---------
Carminic Acid 1260-17-9 90 - 100% Yes
3. Hazards Identification
Emergency Overview
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CAUTION! MAY CAUSE IRRITATION TO SKIN, EYES, AND RESPIRATORY TRACT.
J.T. Baker SAF-T-DATA(tm) Ratings (Provided here for your convenience)
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Health Rating: 1 - Slight
Flammability Rating: 1 - Slight
Reactivity Rating: 0 - None
Contact Rating: 1 - Slight
Lab Protective Equip: GOGGLES; LAB COAT
Storage Color Code: Orange (General Storage)
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Potential Health Effects
----------------------------------
Inhalation:
May cause irritation to the respiratory tract. Symptoms may include
coughing and shortness of breath.
Ingestion:
Large oral doses may cause irritation to the gastrointestinal tract.
Skin Contact:
May cause mild irritation and redness.
Eye Contact:
May cause irritation, redness and pain.
Chronic Exposure:
No information found.
Aggravation of Pre-existing Conditions:
No information found.
4. First Aid Measures
Inhalation:
If a person breathes in large amounts, move the exposed person to fresh
air.
Ingestion:
If large amounts were swallowed, give water to drink and get medical
advice.
Skin Contact:
In case of contact, immediately wash skin with plenty of soap and water for
at least 15 minutes.
Eye Contact:
In case of eye contact, immediately flush with plenty of water for at least
15 minutes.
5. Fire Fighting Measures
Fire:
As with most organic solids, fire is possible at elevated temperatures or
by contact with an ignition source.
Explosion:
None identified.
Fire Extinguishing Media:
Use extinguishing media appropriate for surrounding fire.
Special Information:
Firefighters should wear proper protective equipment and self-contained
breathing apparatus with full facepiece operated in positive pressure mode.
6. Accidental Release Measures
Remove all sources of ignition. Ventilate area of leak or spill. Wear
appropriate personal protective equipment as specified in Section 8.
Spills: Clean up spills in a manner that does not disperse dust into the
air. Use non-sparking tools and equipment. Reduce airborne dust and prevent
scattering by moistening with water. Pick up spill for recovery or disposal
and place in a closed container.
7. Handling and Storage
Keep container tightly closed. Suitable for any general chemical storage
area. Containers of this material may be hazardous when empty since they
retain product residues (dust, solids); observe all warnings and
precautions listed for the product.
8. Exposure Controls/Personal Protection
Airborne Exposure Limits:
None established.
Ventilation System:
Not expected to require any special ventilation.
Personal Respirators (NIOSH Approved):
For conditions of use where exposure to the substance is apparent, consult
an industrial hygienist. For emergencies, or instances where the exposure
levels are not known, use a full-facepiece positive-pressure, air-supplied
respirator. WARNING: Air purifying respirators do not protect workers in
oxygen-deficient atmospheres.
Skin Protection:
Wear protective gloves and clean body-covering clothing.
Eye Protection:
Use chemical safety goggles and/or full face shield where dusting or
splashing of solutions is possible. Maintain eye wash fountain and
quick-drench facilities in work area.
9. Physical and Chemical Properties
Appearance:
Red Powder.
Odor:
No information found.
Solubility:
Appreciable (>10%)
Specific Gravity:
No information found.
pH:
4.8 Yellow.W; 6.2 violet
% Volatiles by volume @ 21C (70F):
0
Boiling Point:
No information found.
Melting Point:
No information found.
Vapor Density (Air=1):
Not applicable.
Vapor Pressure (mm Hg):
Not applicable.
Evaporation Rate (BuAc=1):
No information found.
10. Stability and Reactivity
Stability:
Stable under ordinary conditions of use and storage.
Hazardous Decomposition Products:
Carbon monoxide, carbon dioxide.
Hazardous Polymerization:
Will not occur.
Incompatibilities:
Strong oxidizing agents.
Conditions to Avoid:
No information found.
11. Toxicological Information
--------\Cancer Lists\------------------------------------------------------
---NTP Carcinogen---
Ingredient Known Anticipated IARC Category
------------------------------------ ----- ----------- -------------
Carminic Acid (1260-17-9) No No None
12. Ecological Information
Environmental Fate:
No information found.
Environmental Toxicity:
No information found.
13. Disposal Considerations
Whatever cannot be saved for recovery or recycling should be managed in an
appropriate and approved waste disposal facility. Processing, use or
contamination of this product may change the waste management options.
State and local disposal regulations may differ from federal disposal
regulations.
Dispose of container and unused contents in accordance with federal, state
and local requirements.
14. Transport Information
Not regulated.
15. Regulatory Information
--------\Chemical Inventory Status - Part 1\---------------------------------
Ingredient TSCA EC Japan Australia
----------------------------------------------- ---- --- ----- ---------
Carminic Acid (1260-17-9) Yes Yes Yes Yes
--------\Chemical Inventory Status - Part 2\---------------------------------
--Canada--
Ingredient Korea DSL NDSL Phil.
----------------------------------------------- ----- --- ---- -----
Carminic Acid (1260-17-9) No Yes No Yes
--------\Federal, State & International Regulations - Part 1\----------------
-SARA 302- ------SARA 313------
Ingredient RQ TPQ List Chemical Catg.
----------------------------------------- --- ----- ---- --------------
Carminic Acid (1260-17-9) No No No No
--------\Federal, State & International Regulations - Part 2\----------------
-RCRA- -TSCA-
Ingredient CERCLA 261.33 8(d)
----------------------------------------- ------ ------ ------
Carminic Acid (1260-17-9) No No No
Chemical Weapons Convention: No TSCA 12(b): No CDTA: No
SARA 311/312: Acute: Yes Chronic: No Fire: No Pressure: No
Reactivity: No (Pure / Solid)
Australian Hazchem Code: No information found.
Poison Schedule: No information found.
WHMIS:
This MSDS has been prepared according to the hazard criteria of
the Controlled Products Regulations (CPR) and the MSDS contains
all of the information required by the CPR.
16. Other Information
NFPA Ratings:
Health: 1 Flammability: 1 Reactivity: 0
Label Hazard Warning:
CAUTION! MAY CAUSE IRRITATION TO SKIN, EYES, AND RESPIRATORY TRACT.
Label Precautions:
During use avoid contact with eyes, skin, clothing. Wash thoroughly after
handling. When not in use keep in tightly closed container.
Label First Aid:
If a person breathes in large amounts, move the exposed person to fresh air.
In case of contact, immediately flush eyes or skin with plenty of water for
at least 15 minutes.
Product Use:
Laboratory Reagent.
Revision Information:
Pure. New 16 section MSDS format, all sections have been revised.
Disclaimer:
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Mallinckrodt Baker, Inc. provides the information contained herein in good
faith but makes no representation as to its comprehensiveness or accuracy. This
document is intended only as a guide to the appropriate precautionary handling
of the material by a properly trained person using this product. Individuals
receiving the information must exercise their independent judgment in
determining its appropriateness for a particular purpose. MALLINCKRODT BAKER,
INC. MAKES NO REPRESENTATIONS OR WARRANTIES, EITHER EXPRESS OR IMPLIED,
INCLUDING WITHOUT LIMITATION ANY WARRANTIES OF MERCHANTABILITY, FITNESS FOR A
PARTICULAR PURPOSE WITH RESPECT TO THE INFORMATION SET FORTH HEREIN OR THE
PRODUCT TO WHICH THE INFORMATION REFERS. ACCORDINGLY, MALLINCKRODT BAKER, INC.
WILL NOT BE RESPONSIBLE FOR DAMAGES RESULTING FROM USE OF OR RELIANCE UPON THIS
INFORMATION.
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Prepared by: Strategic Services Division
Phone Number: (314) 539-1600 (U.S.A.)