International Chemical Safety Cards

ALPHA-HEXACHLOROCYCLOHEXANE ICSC: 0795
ALPHA-HEXACHLOROCYCLOHEXANE
1-alpha,2-alpha,3-beta,4-alpha,5-beta,6-beta-Hexachlorocyclohexane
alpha-1,2,3,4,5,6-Hexachlorocyclohexane
alpha-1,2,3,4,5,6-Benzenehexachloride
C6H6Cl6
Molecular mass: 290.9
CAS # 319-84-6
RTECS # GV3500000
ICSC # 0795
EC # 602-042-00-0
TYPES OF
HAZARD/
EXPOSURE
ACUTE HAZARDS/
SYMPTOMS
PREVENTION FIRST AID/
FIRE FIGHTING
FIRE Not combustible. Gives off irritating or toxic fumes (or gases) in a fire.

In case of fire in the surroundings: all extinguishing agents allowed.
EXPLOSION


EXPOSURE
PREVENT DISPERSION OF DUST!

  • INHALATION
  • Weakness. Tremors. Convulsions (see Ingestion).
    Local exhaust or breathing protection.
    Fresh air, rest. Refer for medical attention.
  • SKIN
  • MAY BE ABSORBED! Redness.
    Protective gloves. Protective clothing.
    Remove contaminated clothes. Rinse and then wash skin with water and soap. Refer for medical attention.
  • EYES
  • Redness.
    Safety goggles or face shield.
    First rinse with plenty of water for several minutes (remove contact lenses if easily possible), then take to a doctor.
  • INGESTION
  • Diarrhoea. Dizziness. Headache. Nausea. Vomiting.
    Do not eat, drink, or smoke during work.
    Rinse mouth. Induce vomiting (ONLY IN CONSCIOUS PERSONS!). Refer for medical attention.
    SPILLAGE DISPOSAL STORAGE PACKAGING & LABELLING
    Sweep spilled substance into containers. Carefully collect remainder, then remove to safe place. Do NOT let this chemical enter the environment (extra personal protection: P2 filter respirator for harmful particles).


    T symbol
    R: 21-25-40
    S: 22-36/37-44
    SEE IMPORTANT INFORMATION ON BACK
    ICSC: 0795 Prepared in the context of cooperation between the International Programme on Chemical Safety & the Commission of the European Communities © IPCS CEC 1993

    International Chemical Safety Cards

    ALPHA-HEXACHLOROCYCLOHEXANE ICSC: 0795

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    PHYSICAL STATE; APPEARANCE:
    CRYSTALLINE POWDER.




    CHEMICAL DANGERS:
    The substance decomposes on heating or on burning producing toxic fumes (phosgene - see ICSC # 0007, hydrogen chloride - see ICSC # 0163). Reacts violently with dimethylformamide in the presence of iron.

    OCCUPATIONAL EXPOSURE LIMITS (OELs):
    TLV not established.


    ROUTES OF EXPOSURE:
    The substance can be absorbed into the body by inhalation of its aerosol, through the skin and by ingestion.

    INHALATION RISK:
    Evaporation at 20C is negligible; a harmful concentration of airborne particles can, however, be reached quickly.

    EFFECTS OF SHORT-TERM EXPOSURE:
    The substance irritates the eyes, the skin and the respiratory tract. The substance may cause effects on the central nervous system. Exposure may result in death.

    EFFECTS OF LONG-TERM OR REPEATED EXPOSURE:
    The substance may have effects on the blood, liver. This substance is possibly carcinogenic to humans.
    PHYSICAL
    PROPERTIES
    Boiling point: 288C
    Melting point: 156-161C
    Relative density (water = 1): 1.87
    Solubility in water: none
    Vapour pressure, Pa at 20C: 3
    Octanol/water partition coefficient as log Pow: 3.82
    ENVIRONMENTAL
    DATA
    This substance may be hazardous to the environment; special attention should be given to water organisms and shellfish. In the food chain important to humans, bioaccumulation takes place, specifically in seafood.
    NOTES
    This compound is a component of the insecticide hexachlorocyclohexane (mixed isomers). It is not commercially formulated alone. Data are insufficiently available on the effect of this substance on human health, therefore utmost care must be taken. Do NOT take working clothes home. Also consult ICSC # 0487.
    ADDITIONAL INFORMATION


    ICSC: 0795 ALPHA-HEXACHLOROCYCLOHEXANE
    © IPCS, CEC, 1993
    IMPORTANT LEGAL NOTICE: Neither the CEC or the IPCS nor any person acting on behalf of the CEC or the IPCS is responsible for the use which might be made of this information. This card contains the collective views of the IPCS Peer Review Committee and may not reflect in all cases all the detailed requirements included in national legislation on the subject. The user should verify compliance of the cards with the relevant legislation in the country of use.