PERMATEX INDUSTRIAL CORPORATION 07/02/97 ROCKY HILL, CONNECTICUT 06067 TELEPHONE: (860) 571-5100 MATERIAL SAFETY DATA SHEET Page 01 of 04 Quick Set(TM) Epoxy Resin 81120 RESIN 1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION Product Name: Quick Set(TM) Epoxy Resin Item No.: 81120 RESIN Part of Kit: 81120 Product Type: Epoxy adhesive 2. COMPOSITION, INFORMATION ON INGREDIENTS Ingredients CAS No. % Epoxy resin 26142-30-3 10-15 Epoxy resin 25068-38-6 3-85 Epoxy resin 28906-96-9 3-5 Epoxy resin 25085-99-8 0-80 Ingredients which have exposure limits Exposure Limits (TWA) ACGIH OSHA OTHER Ingredients (TLV) (PEL) Exposure Limits (STEL) ACGIH OSHA Ingredients (TLV) (PEL) 3. HAZARDS IDENTIFICATION Toxicity: Possible skin and eye irritant.May cause skin or eye injury. Possible sensitizer. Primary Routes of Entry: None known Signs and symptoms of Exposure: May cause dermatitis or sensitization on prolonged contact. Heated vapors may cause headache, nausea, dizziness, or respiratory irritation. Existing Conditions Aggravated by Exposure: Allergy, eczema, skin conditions. Literature Referenced Carcinogen Ingredients Target Organ and Other Health Effects NTP IARC OSHA Epoxy resin ALG IRR NO NO NO Epoxy resin ALG IRR NO NO NO Epoxy resin No Data NO NO NO Epoxy resin ALG IRR NO NO NO ------------------------------------------------------------------------------- PERMATEX INDUSTRIAL CORPORATION 07/02/97 ROCKY HILL, CONNECTICUT 06067 TELEPHONE: (860) 571-5100 MATERIAL SAFETY DATA SHEET Page 02 of 04 Product Name: Quick Set(TM) Epoxy Resin Item No.: 81120 RESIN 3. HAZARDS IDENTIFICATION (continued) Abbreviations ALG Allergen IRR Irritant 4. FIRST AID MEASURES Ingestion: Do not induce vomiting. Keep individual calm. Obtain medical attention. Inhalation: Remove to fresh air. If symptoms persist, obtain medical attention. Skin Contact: Wash with soap and water. Eye Contact: Flush at leat 15 minutes with water. Obtain medical attention. 5. FIRE FIGHTING MEASURES Flash Point: More than 200°F Method: Tag Closed Cup Recommended Extinguishing Agents: Carbon dioxide, foam, dry chemical Hazardous Products formed by Fire or Thermal Decomp Phenolics, oxides of carbon, hydrogen chloride, aldehydes Unusual Fire or Explosion Hazards: None Explosive Limits: (% by volume in air)Lower Not available (% by volume in air)Upper Not available 6. ACCIDENTAL RELEASE MEASURES Steps to be taken in case of spill or leak: Soak up with an inert absorbent. Store in a closed container until disposal. 7. HANDLING AND STORAGE Safe Storage: Store below 100°F (Contact Loctite Customer Service 1-800-243-4874 for shelf Life information) Handling: Avoid prolonged skin contact. Keep away from eyes. 8. EXPOSURE CONTROLS, PERSONAL PROTECTION Eyes: Safety glasses or goggles. Skin: Rubber or plastic gloves. Ventilation: Not normally necessary, but mechanical and local PERMATEX INDUSTRIAL CORPORATION 07/02/97 ROCKY HILL, CONNECTICUT 06067 TELEPHONE: (860) 571-5100 MATERIAL SAFETY DATA SHEET Page 03 of 04 Product Name: Quick Set(TM) Epoxy Resin Item No.: 81120 RESIN 8. EXPOSURE CONTROLS, PERSONAL PROTECTION (continued) exhaust ventilation may be desirable for prolonged use in a confined area. See Section 2 for Exposure Limits. 9. PHYSICAL AND CHEMICAL PROPERTIES Appearance: Clear water white to amber liquid Odor: Mild Boiling Point: More than 300°F pH: Does not apply Solubility in Water: Slight Specific Gravity 1.13-1.17 Volatile Organic Compound (EPA Method 24) 0.765%; 8.64 - 8.95 grams per liter Vapor Pressure: Less than 5mm at 80°F Vapor Density: Not available Evaporation Rate (Ether = 1) Not available 10. STABILITY AND REACTIVITY Stability: Stable Hazardous Polymerization: Will not occur Incompatibility: Oxidizing agents, bases, acids, amines, mercaptans Conditions to Avoid: Not available Hazardous Decomposition Products (non-thermal): None 11. TOXICOLOGICAL INFORMATION See Section 3. 12. ECOLOGICAL INFORMATION No data available 13. DISPOSAL CONSIDERATIONS Recommended methods of disposal: Incinerate following EPA and local regulations. EPA Hazardous Waste Number NH - Not a RCRA Hazardous Waste Material PERMATEX INDUSTRIAL CORPORATION 07/02/97 ROCKY HILL, CONNECTICUT 06067 TELEPHONE: (860) 571-5100 MATERIAL SAFETY DATA SHEET Page 04 of 04 Product Name: Quick Set(TM) Epoxy Resin Item No.: 81120 RESIN 14. TRANSPORTATION INFORMATION DOT (49 CFR 172) Domestic Ground Transport Proper Shipping Name: Unrestricted Hazard Class or Division: Unrestricted Identification Number: None Marine Pollutant: None IATA Proper Shipping Name: Unrestricted Class or Division: Unrestricted UN or ID Number: None 15. REGULATORY INFORMATION CA Proposition 65: Warning: This product contains a chemical known to the State of California to cause cancer. Teaces of epichlorohydrin 16. OTHER INFORMATION Estimated NFPA(R) Code: Health Hazard: 1 Fire Hazard: 1 Reactivity Hazard: 0 Specific Hazard: Does not apply Estimated HMIS(R) Code: Health Hazard: 1* Flammability Hazard: 1 Reactivity Hazards: 0 Personal Protection: See Section 8. NFPA is a registered trademark of the National Fire Protection Assn. HMIS is a registered trademark of the National Paint and Coatings Assn. Prepared By: Stephen Repetto Title: Research Chemist, Health and Safety Company: Loctite Corporation 1001 Trout Brook Crossing, Rocky Hill CT 06067 (24hr.) Phone: (860) 571-5100 Revision Date: February 26, 1997 Revision: 0002 PERMATEX INDUSTRIAL CORPORATION 07/02/97 ROCKY HILL, CONNECTICUT 06067 TELEPHONE: (860) 571-5100 MATERIAL SAFETY DATA SHEET Page 01 of 05 Quick Set(TM) Epoxy Hardener 81120 HARDENER 1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION Product Name: Quick Set(TM) Epoxy Hardener Item No.: 81120 HARDENER Part of Kit: 81120 Product Type: Epoxy hardener 2. COMPOSITION, INFORMATION ON INGREDIENTS Ingredients CAS No. % Polymercaptan Proprietary 80-85 Substituted aminophenol 90-72-2 5-10 Nonylphenol 25154-52-3 3-5 Heptakis(dipropyleneglycol)- triphosphate 13474-96-9 1-3 Ingredients which have exposure limits Exposure Limits (TWA) ACGIH OSHA OTHER Ingredients (TLV) (PEL) Exposure Limits (STEL) ACGIH OSHA Ingredients (TLV) (PEL) 3. HAZARDS IDENTIFICATION Toxicity: Skin and eye irritant. Possible respiratory irritant. The aminophenol can cause severe irritation and may be corrosive on prolonged contact. It may be a sensitizer. It can also be corrosive to eye tissue leading to permanent injury including blindness. It may irritate the respiratory tract and may cause delayed lung damage upon overexposure to fumes or vapors. It can also cause fatigue, muscular weakness, labored breathing, or gastrointestinal irritation if swallowed. The relatively low concentration of the aminophenol in the product may minimize some or all of these effects. Primary Routes of Entry: Skin, ingestion, inhalation. Signs and symptoms of Exposure: Eye, skin, respiratory, or gastrointestinal irritation. It is possible that such irritation may be severe and lead to burns. Allergic reactions may occur. PERMATEX INDUSTRIAL CORPORATION 07/02/97 ROCKY HILL, CONNECTICUT 06067 TELEPHONE: (860) 571-5100 MATERIAL SAFETY DATA SHEET Page 02 of 05 Product Name: Quick Set(TM) Epoxy Hardener Item No.: 81120 HARDENER 3. HAZARDS IDENTIFICATION (continued) Existing Conditions Aggravated by Exposure: Skin, eye, lung conditions. Literature Referenced Carcinogen Ingredients Target Organ and Other Health Effects NTP IARC OSHA Polymercaptan No Data NO NO NO Substituted aminophenol IRR NO NO NO Nonylphenol ALG COR IRR NO NO NO Heptakis(dipropyleneglycol)- triphosphate No Data NO NO NO ------------------------------------------------------------------------------- Abbreviations ALG Allergen COR Corrosive IRR Irritant 4. FIRST AID MEASURES Ingestion: Do not induce vomiting. Keep individual calm. Obtain medical attention. Inhalation: Remove to fresh air. If symptoms persist, obtain medical attention. Skin Contact: Wash with soap and water. Eye Contact: Flush at least 15 minutes with water. Obtain medical attention. 5. FIRE FIGHTING MEASURES Flash Point: More than 200°F Method: Tag Closed Cup Recommended Extinguishing Agents: Carbon dioxide, foam, dry chemical Hazardous Products formed by Fire or Thermal Decomp Oxides of carbon, sulfur, and phosphorus, hydrogen sulfide, phosphite/phosphate esters, hydrocarbon fragments. Unusual Fire or Explosion Hazards: None Explosive Limits: (% by volume in air)Lower Not available (% by volume in air)Upper Not available PERMATEX INDUSTRIAL CORPORATION 07/02/97 ROCKY HILL, CONNECTICUT 06067 TELEPHONE: (860) 571-5100 MATERIAL SAFETY DATA SHEET Page 03 of 05 Product Name: Quick Set(TM) Epoxy Hardener Item No.: 81120 HARDENER 6. ACCIDENTAL RELEASE MEASURES Steps to be taken in case of spill or leak: Take up with an inert absorbent. Store in a closed container until disposal. 7. HANDLING AND STORAGE Safe Storage: Store below 110°F. (Contact Loctite Customer Service 1-800-243-4874 for shelf Life information) Handling: Avoid skin contact. Keep away from eyes. Do not breathe vapors. 8. EXPOSURE CONTROLS, PERSONAL PROTECTION Eyes: Safety glasses or goggles. Skin: Rubber or plastic gloves. Ventilation: Local exhaust ventilation should be provided. See Section 2 for Exposure Limits. 9. PHYSICAL AND CHEMICAL PROPERTIES Appearance: Colorless, viscous liquid. Odor: Unpleasant Boiling Point: More than 300°F pH: Does not apply Solubility in Water: Slight Specific Gravity 1.08 Volatile Organic Compound (EPA Method 24) 11.08%; 119.7 grams per liter Vapor Pressure: Less than 5mm at 80°F Vapor Density: Not available Evaporation Rate (Ether = 1) Not available 10. STABILITY AND REACTIVITY Stability: Stable Hazardous Polymerization: Will not occur Incompatibility: Strong oxidizing agents, epoxy/amine mixtures. Possibly acids, peroxides, acetaldehyde, caustics. Conditions to Avoid: Not available Hazardous Decomposition Products (non-thermal): None PERMATEX INDUSTRIAL CORPORATION 07/02/97 ROCKY HILL, CONNECTICUT 06067 TELEPHONE: (860) 571-5100 MATERIAL SAFETY DATA SHEET Page 04 of 05 Product Name: Quick Set(TM) Epoxy Hardener Item No.: 81120 HARDENER 11. TOXICOLOGICAL INFORMATION See Section 3. 12. ECOLOGICAL INFORMATION No data available 13. DISPOSAL CONSIDERATIONS Recommended methods of disposal: Incinerate following EPA and local regulations. EPA Hazardous Waste Number NH - Not a RCRA Hazardous Waste Material 14. TRANSPORTATION INFORMATION DOT (49 CFR 172) Domestic Ground Transport Proper Shipping Name: Unrestricted Hazard Class or Division: Unrestricted Identification Number: None Marine Pollutant: None IATA Proper Shipping Name: Unrestricted Class or Division: Unrestricted UN or ID Number: None 15. REGULATORY INFORMATION CA Proposition 65: No Californis Proposition 65 chemicals are known to be present. 16. OTHER INFORMATION Estimated NFPA(R) Code: Health Hazard: 2 Fire Hazard: 1 Reactivity Hazard: 0 Specific Hazard: Does not apply Estimated HMIS(R) Code: Health Hazard: 2* Flammability Hazard: 1 Reactivity Hazards: 0 Personal Protection: See Section 8. NFPA is a registered trademark of the National Fire Protection Assn. HMIS is a registered trademark of the National Paint and Coatings Assn. PERMATEX INDUSTRIAL CORPORATION 07/02/97 ROCKY HILL, CONNECTICUT 06067 TELEPHONE: (860) 571-5100 MATERIAL SAFETY DATA SHEET Page 05 of 05 Product Name: Quick Set(TM) Epoxy Hardener Item No.: 81120 HARDENER 16. OTHER INFORMATION (continued) Prepared By: Stephen Repetto Title: Research Chemist, Environmental Health & Safety Company: Loctite Corporation 1001 Trout Brook Crossing, Rocky Hill CT 06067 (24hr.) Phone: (860) 571-5100 Revision Date: February 26, 1997 Revision: First Issue