PERMATEX INDUSTRIAL CORPORATION 07/02/97 ROCKY HILL, CONNECTICUT 06067 TELEPHONE: (860) 571-5100 MATERIAL SAFETY DATA SHEET Page 01 of 05 Naval Jelly(R) Rust Remover 81287 1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION Product Name: Naval Jelly(R) Rust Remover Item No.: 81287 Product Type: Rust Dissolver NAVAL JELLY is a registered trademark of Naval Jelly Company 2. COMPOSITION, INFORMATION ON INGREDIENTS Ingredients CAS No. % Water 7732-18-5 65-70 PHOSPHORIC ACID* 7664-38-2 25-30 ISOPROPYL ALCOHOL 67-63-0 1-3 Polysaccharide 11138-66-2 1-3 SULFURIC ACID* 7664-93-9 1-3 Surfactant Proprietary 1-3 SILICA, AMORPHOUS, FUMED, CRYSTALLINE-FREE 112945-52-5 0.1-1 * This component is listed as a SARA Section 313 Toxic Chemical. Ingredients which have exposure limits Exposure Limits (TWA) ACGIH OSHA OTHER Ingredients (TLV) (PEL) PHOSPHORIC ACID 1 mg/m3 TWA 1 mg/m3 TWA 1 mg/m3 ISOPROPYL ALCOHOL 400 ppm TWA 400 ppm TWA None 983 mg/m3 980 mg/m3 SULFURIC ACID 1 mg/m3 TWA 1 mg/m3 TWA None SILICA, AMORPHOUS, FUMED, CRYSTALLINE-FREE 10 mg/m3 TWA 6 mg/m3 TWA 3 mg/m3 TWA resp. dust Exposure Limits (STEL) ACGIH OSHA Ingredients (TLV) (PEL) PHOSPHORIC ACID 3 mg/m3 3 mg/m3 ISOPROPYL ALCOHOL 500 ppm 500 ppm 1230 mg/m3 1225 mg/m3 SULFURIC ACID 3 mg/m3 None PERMATEX INDUSTRIAL CORPORATION 07/02/97 ROCKY HILL, CONNECTICUT 06067 TELEPHONE: (860) 571-5100 MATERIAL SAFETY DATA SHEET Page 02 of 05 Product Name: Naval Jelly(R) Rust Remover Item No.: 81287 3. HAZARDS IDENTIFICATION Toxicity: Skin, eye, and inhalation irritant. Toxic by ingestion. Primary Routes of Entry: Acids and alcohol: Inhalation, ingestion, contact. Signs and symptoms of Exposure: May be injurious to eyes, skin, mucous membranes, and lungs. Existing Conditions Aggravated by Exposure: Respiratory disorders Literature Referenced Carcinogen Ingredients Target Organ and Other Health Effects NTP IARC OSHA Water No Data NO NO NO PHOSPHORIC ACID COR IRR NO NO NO ISOPROPYL ALCOHOL ALG CNS IRR NO N/A NO Polysaccharide IRR NO NO NO SULFURIC ACID COR IRR LUN NO NO NO Surfactant No Data NO NO NO SILICA, AMORPHOUS, FUMED, CRYSTALLINE-FREE NUI NO N/A NO ------------------------------------------------------------------------------- Abbreviations N/A Not Applicable ALG Allergen CNS Central nervous system COR Corrosive IRR Irritant LUN Lung NUI Nuisance dust 4. FIRST AID MEASURES Ingestion: Do not induce vomiting. Keep individual calm. Obtain medical attention. Inhalation: Remove to fresh air. Keep individual calm. Obtain medical attention. Skin Contact: Flush thoroughly with large quantities of water. Obtain medical attention. Eye Contact: Flush with water for at least 15 minutes. Obtain medical attention. 5. FIRE FIGHTING MEASURES Flash Point: None Method: None Recommended Extinguishing Agents: Carbon dioxide, foam, dry chemical Hazardous Products formed by Fire or Thermal Decomp Oxides of phosphorous. PERMATEX INDUSTRIAL CORPORATION 07/02/97 ROCKY HILL, CONNECTICUT 06067 TELEPHONE: (860) 571-5100 MATERIAL SAFETY DATA SHEET Page 03 of 05 Product Name: Naval Jelly(R) Rust Remover Item No.: 81287 5. FIRE FIGHTING MEASURES (continued) Unusual Fire or Explosion Hazards: Not flammable, but hygrogen gas may be liberated if product contacts powdered metals or metals above 185°F. Explosive Limits: (% by volume in air)Lower Not available (% by volume in air)Upper Not available 6. ACCIDENTAL RELEASE MEASURES Steps to be taken in case of spill or leak: Maintain adequate ventilation. Neutralize with alkaline material such as soda ash or lime. Soak up with an inert material. Flush area with water. Store in closed container until disposal. 7. HANDLING AND STORAGE Safe Storage: Keep from freezing. (Contact Loctite Customer Service 1-800-243-4874 for shelf Life information) Handling: Avoid contact with skin and eyes. Avoid prolonged breathing of vapors. 8. EXPOSURE CONTROLS, PERSONAL PROTECTION Eyes: Safety glasses or goggles. Skin: Rubber or plastic gloves. Ventilation: Sufficient to maintain vapor concentration below TLV. See Section 2 for Exposure Limits. 9. PHYSICAL AND CHEMICAL PROPERTIES Appearance: Pink gel Odor: Lime Boiling Point: Approximately 212°F. pH: 1.5-2.5 Solubility in Water: Complete Specific Gravity 1.2 Volatile Organic Compound (EPA Method 24) 24.4%(maximum) Vapor Pressure: Low Vapor Density: Not available Evaporation Rate (Ether = 1) Not available PERMATEX INDUSTRIAL CORPORATION 07/02/97 ROCKY HILL, CONNECTICUT 06067 TELEPHONE: (860) 571-5100 MATERIAL SAFETY DATA SHEET Page 04 of 05 Product Name: Naval Jelly(R) Rust Remover Item No.: 81287 10. STABILITY AND REACTIVITY Stability: Stable Hazardous Polymerization: Will not occur Incompatibility: Caustics and powdered metals. Conditions to Avoid: Not available Hazardous Decomposition Products (non-thermal): Hydrogen gas 11. TOXICOLOGICAL INFORMATION See Section 3. 12. ECOLOGICAL INFORMATION No data available 13. DISPOSAL CONSIDERATIONS Recommended methods of disposal: Incinerate following EPA and local regulations. EPA Hazardous Waste Number D002 - Hazardous waste per 40CFR 261.22 14. TRANSPORTATION INFORMATION DOT (49 CFR 172) Domestic Ground Transport Proper Shipping Name: Consumer Commodity (Not more than four liters); Phosphoric acid solution)(More than four liters) Hazard Class or Division: ORM-D (Not more than four liters); Class 8, Packing Group III (More than four liters) Identification Number: None (Not more than four liters); UN 1805 (More than four liters) Marine Pollutant: None IATA Proper Shipping Name: Phosphoric acid solution Class or Division: Class 8, Packing Group III UN or ID Number: UN 1805 15. REGULATORY INFORMATION CA Proposition 65: WARNING: This product contains a chemical known to the State of California to cause cancer. D.C. Red No.19 (Rhodamine B) PERMATEX INDUSTRIAL CORPORATION 07/02/97 ROCKY HILL, CONNECTICUT 06067 TELEPHONE: (860) 571-5100 MATERIAL SAFETY DATA SHEET Page 05 of 05 Product Name: Naval Jelly(R) Rust Remover Item No.: 81287 16. OTHER INFORMATION Estimated NFPA(R) Code: Health Hazard: 3 Fire Hazard: 0 Reactivity Hazard: 0 Specific Hazard: Does not apply Estimated HMIS(R) Code: Health Hazard: 3 Flammability Hazard: 0 Reactivity Hazards: 0 Personal Protection: See Section 8. NFPA is a registered trademark of the National Fire Protection Assn. HMIS is a registered trademark of the National Paint and Coatings Assn. Prepared By: Stephen Repetto Title: Research Chemist, Health and Safety Company: Loctite Corp., 1001 Tr Br Cr, Rocky Hill CT 06067 (24hr.) Phone: (860) 571-5100 Revision Date: January 22, 1996 Revision: 0025