PERMATEX INDUSTRIAL CORPORATION 07/02/97 ROCKY HILL, CONNECTICUT 06067 TELEPHONE: (860) 571-5100 MATERIAL SAFETY DATA SHEET Page 01 of 06 Permatex(R) Fast Cure Epoxy Mixercups 82234 1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION Product Name: Permatex(R) Fast Cure Epoxy Mixercups Item No.: 82234 Product Type: Epoxy 2. COMPOSITION, INFORMATION ON INGREDIENTS Ingredients CAS No. % RESIN Epoxy resin 25068-38-6 45-50 Aluminum hydroxide, hydrated 21645-51-2 45-50 TITANIUM DIOXIDE 13463-67-7 5-10 SILICA, AMORPHOUS, FUMED, CRYSTALLINE-FREE 112945-52-5 1-3 HARDENER Aluminum hydroxide, hydrated 21645-51-2 45-50 Polymercaptan Proprietary 30-35 Substituted aminophenol 90-72-2 5-10 Aromatic plasticizer 64741-81-7 5-10 STYRENE MONOMER* 100-42-5 3-5 SILICA, AMORPHOUS, FUMED, CRYSTALLINE-FREE 112945-52-5 1-3 ETHYLENE GLYCOL* 107-21-1 1-3 * This component is listed as a SARA Section 313 Toxic Chemical. Ingredients which have exposure limits Exposure Limits (TWA) ACGIH OSHA OTHER Ingredients (TLV) (PEL) RESIN Aluminum hydroxide, hydrated 10 mg/m3 dust 15 mg/m3 dust None 5 mg/m3 respir. TITANIUM DIOXIDE 10 mg/m3 dust 15 mg/m3 dust None 5 mg/m3 resp SILICA, AMORPHOUS, FUMED, CRYSTALLINE-FREE 10 mg/m3 TWA 6 mg/m3 TWA 3 mg/m3 TWA resp. dust PERMATEX INDUSTRIAL CORPORATION 07/02/97 ROCKY HILL, CONNECTICUT 06067 TELEPHONE: (860) 571-5100 MATERIAL SAFETY DATA SHEET Page 02 of 06 Product Name: Permatex(R) Fast Cure Epoxy Mixercups Item No.: 82234 2. COMPOSITION, INFORMATION ON INGREDIENTS (continued) HARDENER Aluminum hydroxide, hydrated 10 mg/m3 dust 15 mg/m3 dust None 5 mg/m3 respir. STYRENE MONOMER 50 ppm TWA 100 ppm TWA None SILICA, AMORPHOUS, FUMED, CRYSTALLINE-FREE 10 mg/m3 TWA 6 mg/m3 TWA 3 mg/m3 TWA resp. dust ETHYLENE GLYCOL None 50 ppm ceiling None 125mg/m3ceiling Exposure Limits (STEL) ACGIH OSHA Ingredients (TLV) (PEL) RESIN HARDENER ETHYLENE GLYCOL 39.4ppm ceil ar None 100mg/m3 ceil a 3. HAZARDS IDENTIFICATION Toxicity: Eye and skin irritant. Repeated or prolonged exposure by ingestion may cause delayed effects involving the blood, gastrointestinal, nervous, and reproductive systems. May be a potential human skin carcinogen. Primary Routes of Entry: Aromatic plasticizer: Skin, eyes, ingestion. Signs and symptoms of Exposure: May cause dermatitis on prolonged contact in sen- sitive individuals. Existing Conditions Aggravated by Exposure: None known Literature Referenced Carcinogen Ingredients Target Organ and Other Health Effects NTP IARC OSHA RESIN Epoxy resin ALG IRR NO NO NO Aluminum hydroxide, hydrated IRR LUN NO NO NO TITANIUM DIOXIDE AC4 IRR NUI NO NO NO SILICA, AMORPHOUS, FUMED, CRYSTALLINE-FREE NUI NO N/A NO PERMATEX INDUSTRIAL CORPORATION 07/02/97 ROCKY HILL, CONNECTICUT 06067 TELEPHONE: (860) 571-5100 MATERIAL SAFETY DATA SHEET Page 03 of 06 Product Name: Permatex(R) Fast Cure Epoxy Mixercups Item No.: 82234 3. HAZARDS IDENTIFICATION (continued) HARDENER Aluminum hydroxide, hydrated IRR LUN NO NO NO Polymercaptan No Data NO NO NO Substituted aminophenol IRR NO NO NO Aromatic plasticizer No Data NO NO NO STYRENE MONOMER IRR LIV MUT NER NO 2B NO SILICA, AMORPHOUS, FUMED, CRYSTALLINE-FREE NUI NO N/A NO ETHYLENE GLYCOL AC4 CNS DEV IRR KID MET NO NO NO ------------------------------------------------------------------------------- Abbreviations N/A Not Applicable 2B Possibly carcinogenic to humans AC4 ACGIH-Unclassifiable as human carc. ALG Allergen CNS Central nervous system DEV Developmental IRR Irritant KID Kidney LIV Liver LUN Lung MET Metabolic MUT Mutagen NER Nervous System NUI Nuisance dust 4. FIRST AID MEASURES Ingestion: Induce vomiting. Obtain medical attetion. Inhalation: Remove to fresh air. If symptoms persist, obtain medical attention. Skin Contact: Flush with water. Eye Contact: Flush at least 15 minutes with water. Obtain medical attention. 5. FIRE FIGHTING MEASURES Flash Point: More than 200°F Method: Tag Closed Cup Recommended Extinguishing Agents: Carbon dioxide, foam, dry chemical Hazardous Products formed by Fire or Thermal Decomp Irritating organic vapor. Unusual Fire or Explosion Hazards: None Explosive Limits: (% by volume in air)Lower 3.2% Ethylene glycol (% by volume in air)Upper 15.3% Ethylene glycol PERMATEX INDUSTRIAL CORPORATION 07/02/97 ROCKY HILL, CONNECTICUT 06067 TELEPHONE: (860) 571-5100 MATERIAL SAFETY DATA SHEET Page 04 of 06 Product Name: Permatex(R) Fast Cure Epoxy Mixercups Item No.: 82234 6. ACCIDENTAL RELEASE MEASURES Steps to be taken in case of spill or leak: Soak up in an inert absorbent. Store in a partly filled, closed container until disposal. 7. HANDLING AND STORAGE Safe Storage: Store below 100°F (Contact Loctite Customer Service 1-800-243-4874 for shelf Life information) Handling: Keep away from eyes. Avoid prolonged skin contact. 8. EXPOSURE CONTROLS, PERSONAL PROTECTION Eyes: Safety glasses or goggles recommended. Skin: Rubber or plastic gloves recommended. Ventilation: Sufficient to maintain vapor concentration below TLV. See Section 2 for Exposure Limits. 9. PHYSICAL AND CHEMICAL PROPERTIES Appearance: RESIN: White Paste Black Paste Odor: RESIN: Mild HARDENER: Disagreeable Boiling Point: More than 300°F pH: Not Applicable Solubility in Water: Slight Specific Gravity RESIN: = 1.68 HARDENER: = 1.40 Volatile Organic Compound (EPA Method 24) Resin: 0.47%; 7.9 grams per liter Hardener: 14.3%; 200 grams per liter Vapor Pressure: Less than 5 mm at 80°F Vapor Density: Not available Evaporation Rate (Ether = 1) Not available 10. STABILITY AND REACTIVITY Stability: Stable Hazardous Polymerization: Will not occur Incompatibility: None Conditions to Avoid: Not available PERMATEX INDUSTRIAL CORPORATION 07/02/97 ROCKY HILL, CONNECTICUT 06067 TELEPHONE: (860) 571-5100 MATERIAL SAFETY DATA SHEET Page 05 of 06 Product Name: Permatex(R) Fast Cure Epoxy Mixercups Item No.: 82234 10. STABILITY AND REACTIVITY (continued) Hazardous Decomposition Products (non-thermal): None 11. TOXICOLOGICAL INFORMATION See Section 3. 12. ECOLOGICAL INFORMATION No data available 13. DISPOSAL CONSIDERATIONS Recommended methods of disposal: Incinerate following EPA and local regulations. EPA Hazardous Waste Number NH - Not a RCRA Hazardous Waste Material 14. TRANSPORTATION INFORMATION DOT (49 CFR 172) Domestic Ground Transport Proper Shipping Name: Unrestricted Hazard Class or Division: Unrestricted Identification Number: None Marine Pollutant: None IATA Proper Shipping Name: Unrestricted Class or Division: Unrestricted UN or ID Number: None 15. REGULATORY INFORMATION CA Proposition 65: Warning: This product contains a chemical known to the State of California to cause cancer. Epichlorohydrin 16. OTHER INFORMATION Estimated NFPA(R) Code: Health Hazard: HARDENER: 2 RESIN: 1 Fire Hazard: HARDENER: 1 RESIN: 1 Reactivity Hazard: HARDENER: 1 PERMATEX INDUSTRIAL CORPORATION 07/02/97 ROCKY HILL, CONNECTICUT 06067 TELEPHONE: (860) 571-5100 MATERIAL SAFETY DATA SHEET Page 06 of 06 Product Name: Permatex(R) Fast Cure Epoxy Mixercups Item No.: 82234 16. OTHER INFORMATION (continued) RESIN: 1 Specific Hazard: Does not apply Estimated HMIS(R) Code: Health Hazard: HARDENER: 2 RESIN: 1 Flammability Hazard: HARDENER: 1 RESIN: 1 Reactivity Hazards: HARDENER: 1 RESIN: 1 Personal Protection: See Section 8. NFPA is a registered trademark of the National Fire Protection Assn. HMIS is a registered trademark of the National Paint and Coatings Assn. Prepared By: Stephen Repetto Title: Research Chemist, Environmental Health & Safety Company: Loctite Corp., 1001 Tr Br Cr, Rocky Hill CT 06067 (24hr.) Phone: (860) 571-5100 Revision Date: April 15, 1997 Revision: 0034