PERMATEX INDUSTRIAL CORPORATION 07/02/97 ROCKY HILL, CONNECTICUT 06067 TELEPHONE: (860) 571-5100 MATERIAL SAFETY DATA SHEET Page 01 of 06 Rapid Metal(TM) Fast Cure Steel-Filled Epoxy Paste 82731 1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION Product Name: Rapid Metal(TM) Fast Cure Steel-Filled Epoxy Paste Item No.: 82731 Product Type: Epoxy 2. COMPOSITION, INFORMATION ON INGREDIENTS Ingredients CAS No. % RESIN Epoxy resin 25068-38-6 40-45 Calcium carbonate 471-34-1 30-40 Barium sulfate 7727-43-7 10-15 SILICA, AMORPHOUS, precipitated 112926-00-8 1-5 TITANIUM DIOXIDE 13463-67-7 1-5 HARDENER Calcium carbonate 1317-65-3 30-45 Polymercaptan Proprietary 30-35 Barium sulfate 7727-43-7 10-15 Iron oxide 1309-38-2 10-15 DIETHYLENETRIAMINE 111-40-0 5-10 Heptakis(dipropyleneglycol)- triphosphate 13474-96-9 1-5 PHENOL, 4,4'-ISOPROPYLIDENEDI-* 80-05-7 1-5 SILICA, AMORPHOUS, precipitated 112926-00-8 1-3 * This component is listed as a SARA Section 313 Toxic Chemical. Ingredients which have exposure limits Exposure Limits (TWA) ACGIH OSHA OTHER Ingredients (TLV) (PEL) RESIN Calcium carbonate 10 mg/m3 dust 15 mg/m3 dust None 5 mg/m3 respir. Barium sulfate 10 mg/m3 dust 10 mg/m3 dust None 5 mg/m3 respir. SILICA, AMORPHOUS, precipitated 10 mg/m3 TWA 6 mg/m3 TWA None TITANIUM DIOXIDE 10 mg/m3 dust 15 mg/m3 dust None 5 mg/m3 resp HARDENER Calcium carbonate 10 mg/m3 TWA 15 mg/m3 dust None dust 5 mg/m3 respir. PERMATEX INDUSTRIAL CORPORATION 07/02/97 ROCKY HILL, CONNECTICUT 06067 TELEPHONE: (860) 571-5100 MATERIAL SAFETY DATA SHEET Page 02 of 06 Product Name: Rapid Metal(TM) Fast Cure Steel-Filled Epoxy Paste Item No.: 82731 2. COMPOSITION, INFORMATION ON INGREDIENTS (continued) Barium sulfate 10 mg/m3 dust 10 mg/m3 dust None 5 mg/m3 respir. Iron oxide 5 mg/M3 (Fe) 10 mg/M3 (Fe) None particulate DIETHYLENETRIAMINE 1 ppm skin 1 ppm TWA None 4.2mg/m3 skin 4mg/m3 PHENOL, 4,4'-ISOPROPYLIDENEDI- None None 10 mg/m3 SILICA, AMORPHOUS, precipitated 10 mg/m3 TWA 6 mg/m3 TWA None Exposure Limits (STEL) ACGIH OSHA Ingredients (TLV) (PEL) RESIN HARDENER 3. HAZARDS IDENTIFICATION Toxicity: Eye and skin irritant. May irritate upper respiratory tract. May cause skin burns and corneal injury resulting in permanent impairment of vision including blindness. May cause sensitization of skin and respiratory tract. Ingestion may cause burns of mouth and throat. Primary Routes of Entry: Ingestion, skin, inhalation Signs and symptoms of Exposure: Eye or skin irritation or injury. Allergic responses such as sensitization or dermatitis. Existing Conditions Aggravated by Exposure: None known Literature Referenced Carcinogen Ingredients Target Organ and Other Health Effects NTP IARC OSHA RESIN Epoxy resin ALG IRR NO NO NO Calcium carbonate NUI NO NO NO Barium sulfate LUN NO NO NO SILICA, AMORPHOUS, precipitated NUI NO NO NO TITANIUM DIOXIDE AC4 IRR NUI NO NO NO HARDENER Calcium carbonate NUI NO NO NO Polymercaptan No Data NO NO NO Barium sulfate LUN NO NO NO Iron oxide No Data NO NO NO DIETHYLENETRIAMINE ALG IRR NO NO NO Heptakis(dipropyleneglycol)- PERMATEX INDUSTRIAL CORPORATION 07/02/97 ROCKY HILL, CONNECTICUT 06067 TELEPHONE: (860) 571-5100 MATERIAL SAFETY DATA SHEET Page 03 of 06 Product Name: Rapid Metal(TM) Fast Cure Steel-Filled Epoxy Paste Item No.: 82731 3. HAZARDS IDENTIFICATION (continued) triphosphate No Data NO NO NO PHENOL, 4,4'-ISOPROPYLIDENEDI- ALG IRR NO NO NO SILICA, AMORPHOUS, precipitated NUI NO NO NO ------------------------------------------------------------------------------- Abbreviations AC4 ACGIH-Unclassifiable as human carc. ALG Allergen IRR Irritant LUN Lung NUI Nuisance dust 4. FIRST AID MEASURES Ingestion: Do not induce vomiting. Keep individual calm. Obtain medical attention. Inhalation: Does not apply Skin Contact: Wash with soap and water. Eye Contact: Flush at least 15 minutes with water. Obtain medical attention. 5. FIRE FIGHTING MEASURES Flash Point: More than 200°F Method: Tag Closed Cup Recommended Extinguishing Agents: Carbon dioxide, foam, dry chemical Hazardous Products formed by Fire or Thermal Decomp Before use, amine vapors may be evolved at high temperatures; oxides of carbon; unidentified organic compounds. Unusual Fire or Explosion Hazards: None Explosive Limits: (% by volume in air)Lower Not available (% by volume in air)Upper Not available 6. ACCIDENTAL RELEASE MEASURES Steps to be taken in case of spill or leak: Scrape up material and store in closed container until disposal. PERMATEX INDUSTRIAL CORPORATION 07/02/97 ROCKY HILL, CONNECTICUT 06067 TELEPHONE: (860) 571-5100 MATERIAL SAFETY DATA SHEET Page 04 of 06 Product Name: Rapid Metal(TM) Fast Cure Steel-Filled Epoxy Paste Item No.: 82731 7. HANDLING AND STORAGE Safe Storage: Store in a cool, dry area. (Contact Loctite Customer Service 1-800-243-4874 for shelf Life information) Handling: Avoid skin contact. Keep away from eyes. Do not breath vapors. 8. EXPOSURE CONTROLS, PERSONAL PROTECTION Eyes: Safety glasses or goggles. Skin: Rubber or plastic gloves. Ventilation: Sufficient to maintain vapor concentration below TLV. See Section 2 for Exposure Limits. 9. PHYSICAL AND CHEMICAL PROPERTIES Appearance: Resin: Black; Hardener: Beige Odor: Resin: Mild; Hardener: Moderate Boiling Point: More than 300°F pH: Does not apply Solubility in Water: Insoluble Specific Gravity Resin: 1.80; Hardener: 1.81 Volatile Organic Compound (EPA Method 24) Resin: 4.94%; 889 grams per liter Hardener: 0%; 0 grams per liter Vapor Pressure: Not available Vapor Density: Not available Evaporation Rate (Ether = 1) Not available 10. STABILITY AND REACTIVITY Stability: Stable Hazardous Polymerization: Will not occur Incompatibility: Strong oxidizers, acids, chlorinated hydrocarbons. Conditions to Avoid: Not available Hazardous Decomposition Products (non-thermal): None 11. TOXICOLOGICAL INFORMATION See Section 3. 12. ECOLOGICAL INFORMATION No data available PERMATEX INDUSTRIAL CORPORATION 07/02/97 ROCKY HILL, CONNECTICUT 06067 TELEPHONE: (860) 571-5100 MATERIAL SAFETY DATA SHEET Page 05 of 06 Product Name: Rapid Metal(TM) Fast Cure Steel-Filled Epoxy Paste Item No.: 82731 13. DISPOSAL CONSIDERATIONS Recommended methods of disposal: Incinerate following EPA and local regulations. EPA Hazardous Waste Number D005 - May be a TCLP waste per 40CFR 261.24/Barium 14. TRANSPORTATION INFORMATION DOT (49 CFR 172) Domestic Ground Transport Proper Shipping Name: Consumer Commodity (Not more than four liters); Corrosive liquids, basic, organic, n.o.s. (Contains diethylenetriamine) (More than four liters) Hazard Class or Division: ORM-D (Not more than four liters); Class 8, Packing Group III (More than four liters) Identification Number: None (Not more than four liters); UN 3267 (More than four liters) Marine Pollutant: None IATA Proper Shipping Name: Corrosive liquids, basic, organic, n.o.s. (Contains diethylenetriamine) Class or Division: Class 8, Packing Group III UN or ID Number: UN 3267 15. REGULATORY INFORMATION CA Proposition 65: Warning: This product contains a chemical known to the State of California to cause cancer. Epichlorohydrin 16. OTHER INFORMATION Estimated NFPA(R) Code: Health Hazard: 2 Fire Hazard: 1 Reactivity Hazard: 0 Specific Hazard: Does not apply Estimated HMIS(R) Code: Health Hazard: 2 Flammability Hazard: 1 Reactivity Hazards: 0 Personal Protection: See Section 8. NFPA is a registered trademark of the National Fire Protection Assn. HMIS is a registered trademark of the National Paint and Coatings Assn. PERMATEX INDUSTRIAL CORPORATION 07/02/97 ROCKY HILL, CONNECTICUT 06067 TELEPHONE: (860) 571-5100 MATERIAL SAFETY DATA SHEET Page 06 of 06 Product Name: Rapid Metal(TM) Fast Cure Steel-Filled Epoxy Paste Item No.: 82731 16. OTHER INFORMATION (continued) Prepared By: Jean Tobbe Title: Environmental Health & Safety Specialist Company: Loctite Corp., 1001 Tr Br Cr, Rocky Hill CT 06067 (24hr.) Phone: (860) 571-5100 Revision Date: April 15, 1997 Revision: 0006