PERMATEX INDUSTRIAL CORPORATION 07/02/97 ROCKY HILL, CONNECTICUT 06067 TELEPHONE: (860) 571-5100 MATERIAL SAFETY DATA SHEET Page 01 of 06 DuraMetal Machinable Metal Repair Epoxy 82732 1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION Product Name: DuraMetal Machinable Metal Repair Epoxy Item No.: 82732 Product Type: Epoxy 2. COMPOSITION, INFORMATION ON INGREDIENTS Ingredients CAS No. % RESIN Barium sulfate 7727-43-7 4.000 Epoxy resin 25068-38-6 Unknown Epoxy resin 28064-14-4 Unknown Epoxy resin 2425-79-8 Unknown Iron 7439-89-6 Unknown Modified silicon dioxide 67762-90-7 Unknown SILICON POWDER 7440-21-3 Unknown Substituted silane 2530-83-8 Unknown TALC 14807-96-6 Unknown TITANIUM DIOXIDE 13463-67-7 Unknown HARDENER Barium sulfate 7727-43-7 69.40 Alkylenediamine 3236-53-1 Unknown Alkylenediamine 3236-54-2 Unknown DIETHYLENETRIAMINE 111-40-0 Unknown Epoxy resin/curing agent 68610-56-0 Unknown Iron 7439-89-6 Unknown Modified silicon dioxide 67762-90-7 Unknown PHENOL, 4,4'-ISOPROPYLIDENEDI-* 80-05-7 1.0200 Substituted aminophenol 90-72-2 Unknown SILICON POWDER 7440-21-3 Unknown TITANIUM DIOXIDE 13463-67-7 Unknown * This component is listed as a SARA Section 313 Toxic Chemical. Ingredients which have exposure limits Exposure Limits (TWA) ACGIH OSHA OTHER Ingredients (TLV) (PEL) RESIN Barium sulfate 10 mg/m3 dust 10 mg/m3 dust None 5 mg/m3 respir. Iron 10 mg/m3 dust 15 mg/m3 dust None Modified silicon dioxide 10 mg/m3 6 mg/m3 None SILICON POWDER 10 mg/m3 10 mg/m3 dust None 5 mg/m3 respir. PERMATEX INDUSTRIAL CORPORATION 07/02/97 ROCKY HILL, CONNECTICUT 06067 TELEPHONE: (860) 571-5100 MATERIAL SAFETY DATA SHEET Page 02 of 06 Product Name: DuraMetal Machinable Metal Repair Epoxy Item No.: 82732 2. COMPOSITION, INFORMATION ON INGREDIENTS (continued) TALC 2 mg/m3 TWA 2 mg/m3 TWA None respirable dust respirable dust TITANIUM DIOXIDE 10 mg/m3 dust 15 mg/m3 dust None 5 mg/m3 resp HARDENER Barium sulfate 10 mg/m3 dust 10 mg/m3 dust None 5 mg/m3 respir. DIETHYLENETRIAMINE 1 ppm skin 1 ppm TWA None 4.2mg/m3 skin 4mg/m3 Iron 10 mg/m3 dust 15 mg/m3 dust None Modified silicon dioxide 10 mg/m3 6 mg/m3 None PHENOL, 4,4'-ISOPROPYLIDENEDI- None None 10 mg/m3 SILICON POWDER 10 mg/m3 10 mg/m3 dust None 5 mg/m3 respir. TITANIUM DIOXIDE 10 mg/m3 dust 15 mg/m3 dust None 5 mg/m3 resp Exposure Limits (STEL) ACGIH OSHA Ingredients (TLV) (PEL) RESIN HARDENER 3. HAZARDS IDENTIFICATION Toxicity: Resin: Eye irritant, severe skin irritant. Hardener: Corrosive to eyes and skin. Causes burns Resin and hardener may cause sensitization in susceptible individuals. Primary Routes of Entry: Dermal; heated product may produce inhalable vapors. Signs and symptoms of Exposure: Resin: Causes severe skin irritation. Causes eye irritation. May cause skin burns and allergic skin reaction. Hardener: Danger! Corrosive - Causes skin and eye burns. Harmful if swallowed. May cause allergic skin and respiratory reactions. Acute: Danger! Corrosive. Causes skin and eye burns. Existing Conditions Aggravated by Exposure: Eye and skin conditions. Literature Referenced Carcinogen Ingredients Target Organ and Other Health Effects NTP IARC OSHA RESIN Barium sulfate LUN NO NO NO PERMATEX INDUSTRIAL CORPORATION 07/02/97 ROCKY HILL, CONNECTICUT 06067 TELEPHONE: (860) 571-5100 MATERIAL SAFETY DATA SHEET Page 03 of 06 Product Name: DuraMetal Machinable Metal Repair Epoxy Item No.: 82732 3. HAZARDS IDENTIFICATION (continued) Epoxy resin ALG IRR NO NO NO Epoxy resin ALG IRR NO NO NO Epoxy resin ALG IRR NO NO NO Iron EYE LUN NO NO NO Modified silicon dioxide No Data NO NO NO SILICON POWDER IRR NUI NO NO NO Substituted silane IRR NO NO NO TALC AC4 IRR LUN NO N/A NO TITANIUM DIOXIDE AC4 IRR NUI NO NO NO HARDENER Barium sulfate LUN NO NO NO Alkylenediamine No Data NO NO NO Alkylenediamine No Data NO NO NO DIETHYLENETRIAMINE ALG IRR NO NO NO Epoxy resin/curing agent No Data NO NO NO Iron EYE LUN NO NO NO Modified silicon dioxide No Data NO NO NO PHENOL, 4,4'-ISOPROPYLIDENEDI- ALG IRR NO NO NO Substituted aminophenol IRR NO NO NO SILICON POWDER IRR NUI NO NO NO TITANIUM DIOXIDE AC4 IRR NUI NO NO NO ------------------------------------------------------------------------------- Abbreviations N/A Not Applicable AC4 ACGIH-Unclassifiable as human carc. ALG Allergen EYE Eyes IRR Irritant LUN Lung NUI Nuisance dust 4. FIRST AID MEASURES Ingestion: If conscious, give plenty of water to drink. Do not induce vomiting. Obtain medical attetion. Inhalation: Remove to fresh air. Give oxygen and/or artificial respiration if needed. Obtain medical attention. Skin Contact: Wash with soap and water. Remove contaminated clothing and launder before reuse. Eye Contact: Immediately flush at least 15 minutes with water. Obtain medical attention. Referral to a physician is recommended if there is any question about the seriousness of any injury. PERMATEX INDUSTRIAL CORPORATION 07/02/97 ROCKY HILL, CONNECTICUT 06067 TELEPHONE: (860) 571-5100 MATERIAL SAFETY DATA SHEET Page 04 of 06 Product Name: DuraMetal Machinable Metal Repair Epoxy Item No.: 82732 5. FIRE FIGHTING MEASURES Flash Point: More than 200°F Method: Tag Closed Cup Recommended Extinguishing Agents: Carbon dioxide, foam, dry chemical, water. Use self-contained breathing apparatus. Hazardous Products formed by Fire or Thermal Decomp Irritating or toxic organic vapors; oxides of carbon. Unusual Fire or Explosion Hazards: Decomposition and combustion products may be toxic Explosive Limits: (% by volume in air)Lower Not available (% by volume in air)Upper Not available 6. ACCIDENTAL RELEASE MEASURES Steps to be taken in case of spill or leak: Soak up in an inert absorbent. Store in a closed container until disposal. Do not store cleaned up resin and cleaned up hardener in the same container. 7. HANDLING AND STORAGE Safe Storage: Store below 100°F (Contact Loctite Customer Service 1-800-243-4874 for shelf Life information) Handling: Avoid skin or eye contact. Do not breathe hardener vapors or mist. 8. EXPOSURE CONTROLS, PERSONAL PROTECTION Eyes: Resin: Splash-proof chemical goggles. Hardener: Full face shield. Skin: Impermeable gloves and protective clothing. Ventilation: Sufficient general mechanical and local exhaust to maintain vapor concentration below TLV. Wear NIOSH approved organic vapor cartridge respirator when exposure to vapors or mist is likely. See Section 2 for Exposure Limits. 9. PHYSICAL AND CHEMICAL PROPERTIES Appearance: Resin: Dark grey paste. Hardener: Light grey viscous liquid Odor: Resin: Mild. Hardener: Amine Boiling Point: Not available PERMATEX INDUSTRIAL CORPORATION 07/02/97 ROCKY HILL, CONNECTICUT 06067 TELEPHONE: (860) 571-5100 MATERIAL SAFETY DATA SHEET Page 05 of 06 Product Name: DuraMetal Machinable Metal Repair Epoxy Item No.: 82732 9. PHYSICAL AND CHEMICAL PROPERTIES (continued) pH: Does not apply Solubility in Water: Resin: Negligible. Hardener: Moderate. Specific Gravity 2.71 Volatile Organic Compound (EPA Method 24) Resin: 1.58%; 42.8 grams per liter Hardener: 7.14%; 193 grams per liter Vapor Pressure: Not available Vapor Density: Not available Evaporation Rate (Ether = 1) Not available 10. STABILITY AND REACTIVITY Stability: Stable Hazardous Polymerization: Will not occur Incompatibility: Resin: Strong oxidizers, acid and bases. Hardener: Strong oxidizing agents, acids, metal- organic compounds. Conditions to Avoid: Not available Hazardous Decomposition Products (non-thermal): None 11. TOXICOLOGICAL INFORMATION See Section 3. 12. ECOLOGICAL INFORMATION No data available 13. DISPOSAL CONSIDERATIONS Recommended methods of disposal: Incinerate following EPA and local regulations. EPA Hazardous Waste Number D005 - May be TCLP waste per 40CFR 261.24/Barium 14. TRANSPORTATION INFORMATION DOT (49 CFR 172) Domestic Ground Transport Proper Shipping Name: Resin: Unrestricted Hardener: Consumer Commodity (Not more than one liter) Polyamines, liquid, n.o.s. (Contains diethylene triamine and trimethylhexamethylene diamine) (More than one liter) PERMATEX INDUSTRIAL CORPORATION 07/02/97 ROCKY HILL, CONNECTICUT 06067 TELEPHONE: (860) 571-5100 MATERIAL SAFETY DATA SHEET Page 06 of 06 Product Name: DuraMetal Machinable Metal Repair Epoxy Item No.: 82732 14. TRANSPORTATION INFORMATION (continued) Hazard Class or Division: Resin: Unrestricted Hardener: ORM-D (Not more than one liter); Class 8, Packing Group II (More than one liter) Identification Number: Resin: None Hardener: None (Not more than one liter); UN 2735 (More than one liter) Marine Pollutant: None IATA Proper Shipping Name: Resin: Unrestricted Hardener: Polyamine, liquid, corrosive, n,o,s, (Contains diethylene triamine and trimethylhexamethylene diamine) Class or Division: Resin: Unrestricted Hardener: Class 8, Packing Group II UN or ID Number: Resin: None Hardener: UN 2735 15. REGULATORY INFORMATION CA Proposition 65: Warning: This product contains a chemical known to the State of California to cause cancer. Epichlorohydrin 16. OTHER INFORMATION Estimated NFPA(R) Code: Health Hazard: 2 Fire Hazard: 1 Reactivity Hazard: 1 Specific Hazard: Does not apply Estimated HMIS(R) Code: Health Hazard: 2 Flammability Hazard: 1 Reactivity Hazards: 1 Personal Protection: See Section 8. NFPA is a registered trademark of the National Fire Protection Assn. HMIS is a registered trademark of the National Paint and Coatings Assn. Prepared By: Stephen Repetto Title: Research Chemist, Environmental Health & Safety Company: Loctite Corp., 1001 Tr Br Cr, Rocky Hill CT 06067 (24hr.) Phone: (860) 571-5100 Revision Date: April 15, 1997 Revision: 0005