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Section 1. CHEMICAL PRODUCT SECTION
Product Name: Dry TFE Lube & Mold Release
Product Number: 2414 AEROSOL
General Use: Lubricate mold release
Product Description: Suspended TFE lubricant
MANUFACTURER: Tech Spray, Inc. For Chemical Emergency, Spill, Leak, Fire
P.O. Box 949 Exposure, or Accident Call CHEMTREC
Amarillo, TX 79105-0949 DAY OR NIGHT 1-800-424-9300.
PHONE: 806/372-8523
FAX: 806/372-8750
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Section 2. COMPOSITION / INFORMATION ON INGREDIENTS
CHEMICAL C.A.S. Number Weight %
Dichlorofluoroethane 1717-00-6 85-90
Ethanol 64-17-5 < 10
Methanol 67-56-1 1.44
Poly-TFE (primarily omega-hydro-alpha-
(methylcyclohexal) 65530-85-0 2-5
Carbon Dioxide 124-38-9 <3
1,1,1,2-Tetrafluoroethane 811-97-2 18-23
OSHA HAZARDOUS COMPONENTS (29 CFR 1910.1200):
Exposure Limits 8 Hours TWA (PPM)
OSHA PEL ACGIH TLV Supplier
Dichlorofluoroethane 500
Ethanol 1000 1000
Methanol 200
Carbon Dioxide 10,000
1,1,1,2-Tetrafluoroethane 1000
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Section 3. HAZARD IDENTIFICATION
Emergency Overview:
Potential Health Effects:
INHALATION: Major route of exposure. Vapor is heavier than air and can
cause suffocation by reducing the available oxygen for
breathing. Breathing high concentrations of vapor may cause
light-headedness, giddiness, shortness of breath, confusion,
and may lead to narcosis, cardiac irregularities,
or unconsciousness. Inhalation of high concentrations in a
closely confined area may be fatal.
EYES: Liquid contact will irritate eyes and may cause conjunctivitis.
SKIN: Not a corrosive or irritant; however, repeated or prolonged exposure
can cause defatting of skin.
INGESTION: Single dose toxicity is low to moderate. If vomiting occurs
the liquid can be aspirated into lungs, which can cause
chemical pneumonia and systemic effects. Human psychotropic,
gastrointestinal, and central nervous system effects possible.
Large quanities could cause blindness due to Methanol Content.
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Section 4. FIRST AID MEASURES
Inhalation:
Move to fresh air in case of accidental inhalation of vapors. If
victim has stopped breathing, give artificial respiration. Call for
prompt medical attention.
Eye Contact:
Flush eyes with large amounts of water for 15 minutes or until
irritation subsides. If irritation persist, get medical attention.
Skin Contact:
Remove Contaminated clothing (including shoes) and wash before reuse.
Flush with large amounts of water. Use soap if available. If
irritation persist, seek medical attention.
Ingestion:
Do not induce vomiting unless directed by a physician. If conscious
and alert, give two glasses of water. Seek medical attention
immediately.
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Section 5. FIRE FIGHTING MEASURES
Flash Point & Method: NON-FLAMMABLE (TCC)
Flammable Limits: LEL: 7.4 UEL: 15.5
Autoignition Temperature: Not Established
Calculated Heat of Combustion 4.7 kj/g NFPA Level 1 Aerosol
GENERAL HAZARD:
Aerosol cans may erupt with force at temperatures above 120 degrees F.
FIRE FIGHTING INSTRUCTIONS:
Fire fighters should wear self contained, positive-pressure breathing
apparatusand avoid contact with fumes which could contain hydochloric
and hydrofluoric acid.
FIRE FIGHTING EQUIPMENT:
Water, foam, dry chemical, carbon dioxide.
HAZARDOUS COMBUSTION PRODUCTS:
Smoke, fumes and oxides of carbon.
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Section 6. ACCIDENTAL RELEASE MEASURES
LAND SPILL:
Evacuate area. Ventilate area well and avoid breathing vapors. Vapor
concentration will be highest along floor and in low lying areas. Pick up
liquid on suitable absorbent and store in sealed containers.
Shut off fire sources. Workers should wear proper equipment to work in
clean up area.
WATER SPILL:
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Section 7. HANDLING AND STORAGE
STORAGE TEMPERATURE: Ambient
STORAGE PRESSURE: Atmospheric
GENERAL:
Keep container closed when not in use. Store in cool, well ventilated
place out of direct sunlight and away from incompatible materials.
(See STABILITY AND REACTIVITY Section 10.) Follow all MSD Sheet and
Label warnings even after container is emptied.
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Section 8. EXPOSURE CONTROL / PERSONAL PROTECTION
Engineering Controls:
(X) Local Exhaust ventilation acceptable.
( ) Mechanical ventilation recommended.
( ) Use explosion-proof ventilation equipment.
( ) Do not use in confined spaces without mechanical ventilation
equipment.
See section 2 for component exposure guidelines.
Personal Protection:
RESPIRATOR:
If concentrations are over the exposure limit and are known, air
purifying respirator with Organic Vapor Cartridges may be acceptable.
Refer to cartridges for acceptable levels. If concentrations are
over exposure limit and are unknown, use a supplied air respirator.
HAND PROTECTION:
(X) Gloves recommended
(X) Solvex (X) Neoprene
(X) Butyl ( ) Buna
( ) Natural Latex ( ) Cotton/Jersey
EYE PROTECTION:
(X) Safety Glasses ( ) Chemical Goggles ( ) Full Face Shield
OTHER RECOMMENDATIONS:
( ) Rubber Boots ( ) Splash-proof chemical resistant suit/apron
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Section 9. PHYSICAL AND CHEMICAL PROPERTIES
Density................. 1.21 pH......................... NA
Boiling Point........... 35 C / F % Volatile................. 100
Freezing Point.......... -103C / -153F % Solids................... 0
Vapor Density (Air=1):.. 10 PSIA 70F Evaporation Rate (H2O=1)... >1
Solubility in Water..... 10 Viscosity.................. N/A
Molecular Weight........ N/A (mixture) Physical State............. LIQUID
Non-Exempt VOC (g/l).... 100 Odor...................... ethereal
Appearance: Clear water-white mobile liquid with slight ethereal odor.
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Section 10. STABILITY AND REACTIVITY
GENERAL:
STABLE
INCOMPATIBLE MATERIALS AND CONDITIONS TO AVOID:
Contact with open flame, heat.
Reactive alkali metals, strong acids & bases.
HAZARDOUS DECOMPOSITION:
Hydrogen chloride, phosgene, chlorine, carbon dioxide, and carbon monoxide.
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Section 11. TOXICOLOGICAL INFORMATION
RESULTS OF COMPONENT TOXICITY TEST PERFORMED:
Oral Rat LD50: >5g/kg
Deramal LD50: >2g/KG
Inhalation 4 hour LC50: 62000ppm
HUMAN EXPERIENCE:
High exposures can cause central nervous system depression
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Section 12. ECOLOGICAL INFORMATION
FURTHER INFORMATION:
Oral Rat LD50: >5g/kg
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Section 13. DISPOSAL CONSIDERATIONS
RCRA 40 CFR 261 Classification:
Federal, State, and Local laws governing disposal of materials can differ.
Ensure proper disposal compliance with proper authorities before disposal.
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Section 14. TRANSPORTATION INFORMATION
U.S. DOT Information
Proper Shipping Name: CONSUMER COMMODITY ORM-D
Hazard Class: N/A
Packaging Group: N/A
UN Number: N/A
Limitations: N/A
IATA
Proper Shipping Name: Consumer Commodity
Hazard Class: 9
Packing Group: N/A
UN Number: ID8000
Limitations: Domestic Air shipments only.
When shipping International please contact
Tech Spray's shipping department.
IMO
Proper Shipping Name: Aerosols
Class: 9 Primary Class 2.2
UN Number: UN1950
Packaging Group: N/A
EMS: 2-13
MFAG: 306
Marine Pollutant: N/A
Canadian TDG: N/A
IMDG Page: 9022
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Section 15. REGULATORY INFORMATION
UNITED STATES FEDERAL REGULATIONS:
MSDS complies with OSHAs Hazard Communication Rule, 29 CFR 1910.1200.
CERCLA/SUPERFUND, 40 CFR 117, 302:
--- None of the chemicals are Superfund hazards ---
SARA SUPERFUND AND REAUTHORIZATION ACT OF 1986
TITLE III Sections 302, 311, 312 and 313:
Section 302 - Extremely hazardous substances (40 CFR 355):
--- None of the chemicals are Section 302 hazards ---
Section 311/312 - Material Safety Data Sheet Requirements (40 CFR 370)
( ) By our hazard evaluation, this product is non-hazardous.
(X) By our hazard evaluation, this product is hazardous. It
should be reported under the following EPA hazard.
(X) Immediate (acute) health hazard
( ) Delayed (chronic) chronic health hazard
( ) Sudden release of pressure hazard
( ) Reactive hazard
Section 313 - List of Toxic Chemicals (40 CFC 372)
This product contains the following chemicals (at levels of 1% or
greater) which are found on the 313 list of Toxic Chemicals.
CHEMICAL C.A.S. NUMBER WEIGHT %
Dichlorofluoroethane 1717-00-6 85-90
Methanol 67-56-1 1.44
TOXIC SUBSTANCE CONTROL ACT (TSCA): All substances are TSCA Listed.
RESOURCE CONSERVATION AND RECOVERY ACT (RCRA 40 CFR 261) Subpart C & D:
Refer to Section 11. for RCRA classification.
FEDERAL WATER POLLUTION CONTROL ACT, CLEAN WATER ACT, 40 CFR 401.15
(FORMERLY SECTION 307), 40 CFR 116 (FORMERLY SECTION 311)
This product contains the following chemicals which are listed:
CHEMICAL C.A.S. NUMBER WEIGHT %
CLEAN AIR ACT: --- No Information ---
STATE REGULATIONS:
CALIFORNIA PROPOSITION 65:
This product contains the following ingredients which appear on the
California proposition 65 list:
CHEMICAL C.A.S. NUMBER WEIGHT %
--- None of the chemicals are on the Proposition 65 list ---
INTERNATIONAL REGULATIONS:
CANADA WHMIS: REGULATED A, B.5, D.2.B
EUROPE EINECS NUMBERS: Dichlorofluoroethane; 1717-00-6
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Section 16. OTHER INFORMATION
LABEL INFORMATION:
European risk and Safety Phrases: S2, S23, S24/25, S51, R20/22
European Symbols Needed: HARMFUL
Canadian WHIMS Symbols: TOXIC, Compressed Gas
NFPA HAZARD RATING:
(1) Fire (2) Health (1) Reactivity
REVISION DATES, SECTIONS, REVISED BY:
22-AUG-96, Created, B. RIFFEL
ABBREVIATIONS USED IN THIS DOCUMENT:
NE - Not Established, NA - Not Applicable, NIF - No Information Found
REFERENCES:
Code of Federal Regulations (CFR)
The Sigma-Aldrich Library of Regulatory and Safety Data
Chemical Guide and OSHA Hazard Communication Standard
Various Federal, State & Local Regulations
To the best of our knowledge, the information contained herein is accurate.
However, neither Tech Spray, Inc. or any of its subsidiaries assumes any
liability whatsoever for the accuracy or completeness of the information
contained herein. Final determination of suitability of any material is the
sole responsibility of the user. All materials may present unknown hazards and
should be used with caution. Although certain hazards are described herein,
we cannot guarantee that these are the only hazards which exist.
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