NAVAJO REFINING CO -- GASOLINE (UNLEADED,OXYGENATED) -- 9130-00-148-7103
=====================  Product Identification  =====================

Product ID:GASOLINE (UNLEADED,OXYGENATED)
MSDS Date:03/11/1992
FSC:9130
NIIN:00-148-7103
MSDS Number: BRGGT
=== Responsible Party ===
Company Name:NAVAJO REFINING CO
Address:501 E MAIN - DRAWER 159
City:ARTESIA
State:NM
ZIP:88210-0159
Country:US
Info Phone Num:505-748-3311
Emergency Phone Num:505-748-3311/800-424-9300(CHEMTREC)
CAGE:4K236
=== Contractor Identification ===
Company Name:BIG BEAR OIL CO INC
Address:421 FREDRICK ST
Box:2036
City:EL PASO
State:TX
ZIP:79950
Country:US
Phone:915-775-1945
CAGE:0BMM6
Company Name:NAVAJO REFINING COMPANY
Box:159
City:ARTESIA
State:NM
ZIP:88211-0159
Country:US
Phone:505-748-3311
CAGE:4K236

=============  Composition/Information on Ingredients  =============

Ingred Name:GASOLINE
CAS:8006-61-9
RTECS #:LX3300000
Fraction by Wt: 100%
Other REC Limits:NONE RECOMMENDED
OSHA PEL:300 PPM/500 STEL
ACGIH TLV:300 PPM/500STEL;9293

Ingred Name:METHYL TERT-BUTYL ETHER  (SARA III) (CONTAINED IN GASOLINE)
CAS:1634-04-4
RTECS #:KN5250000
Fraction by Wt: 10-11%
Other REC Limits:NONE RECOMMENDED
EPA Rpt Qty:1 LB
DOT Rpt Qty:1 LB

Ingred Name:DENATURED ALCOHOL (CONTAINED IN GASOLINE)
RTECS #:AZ0875400
Fraction by Wt: 6-10%
Other REC Limits:NONE RECOMMENDED
OSHA PEL:1000 PPM (ETHANOL)
ACGIH TLV:1000 PPM (ETHANOL)

Ingred Name:BENZENE  (SARA III) (CONTAINED IN GASOLINE)
CAS:71-43-2
RTECS #:CY1400000
Fraction by Wt: 1-5%
Other REC Limits:NONE RECOMMENDED
OSHA PEL:1PPM/5STEL;1910.1028
ACGIH TLV:10 PPM; A2; 9293
EPA Rpt Qty:10 LBS
DOT Rpt Qty:10 LBS

Ingred Name:ETHYL BENZENE  (SARA III) (CONTAINED IN GASOLINE)
CAS:100-41-4
RTECS #:DA0700000
Fraction by Wt: 1-3%
Other REC Limits:NONE RECOMMENDED
OSHA PEL:100 PPM/125 STEL
ACGIH TLV:100 PPM/125STEL 9293
EPA Rpt Qty:1000 LBS
DOT Rpt Qty:1000 LBS

Ingred Name:CYCLOHEXANE  (SARA III) (CONTAINED IN GASOLINE)
CAS:110-82-7
RTECS #:GU6300000
Fraction by Wt: 1%
Other REC Limits:NONE RECOMMENDED
OSHA PEL:300 PPM
ACGIH TLV:300 PPM, 9293
EPA Rpt Qty:1000 LBS
DOT Rpt Qty:1000 LBS

Ingred Name:TOLUENE  (SARA III) (CONTAINED IN GASOLINE)
CAS:108-88-3
RTECS #:XS5250000
Fraction by Wt: 1-5%
Other REC Limits:NONE RECOMMENDED
OSHA PEL:200 PPM/150 STEL
ACGIH TLV:50 PPM; 9293
EPA Rpt Qty:1000 LBS
DOT Rpt Qty:1000 LBS

Ingred Name:XYLENES (O-,M-,P- ISOMERS)	(SARA III) (CONTAINED IN
    GASOLINE)
CAS:1330-20-7
RTECS #:ZE2100000
Fraction by Wt: 4-6%
Other REC Limits:NONE RECOMMENDED
OSHA PEL:100 PPM/150 STEL
ACGIH TLV:100 PPM/150STEL;9293
EPA Rpt Qty:1000 LBS
DOT Rpt Qty:1000 LBS

Ingred Name:CUMENE  (SARA III) (CONTAINED IN GASOLINE)
CAS:98-82-8
RTECS #:GR8575000
Fraction by Wt: 1%
Other REC Limits:NONE RECOMMENDED
OSHA PEL:S, 50 PPM
ACGIH TLV:S, 50 PPM; 9293
EPA Rpt Qty:5000 LBS
DOT Rpt Qty:5000 LBS

Ingred Name:1,2,4-TRIMETHYLBENZENE  (SARA III) (CONTAINED IN GASOLINE)
CAS:95-63-6
RTECS #:DC3325000
Fraction by Wt: 1%
Other REC Limits:NONE RECOMMENDED
OSHA PEL:25 PPM
ACGIH TLV:25 PPM; 9293

Ingred Name:GASOLINE CONTAINS EITHER INGREDIENT 2: METHYL-TERT-BUTYL
    ETHER OR INGREDIENT 3: DENATURED ETHANOL.
RTECS #:9999999ZZ

=====================  Hazards Identification  =====================

LD50 LC50 Mixture:TLV FOR GASOLINE IS 300 PPM
Routes of Entry: Inhalation:YES  Skin:YES  Ingestion:NO
Reports of Carcinogenicity:NTP:YES    IARC:YES	  OSHA:YES
Health Hazards Acute and Chronic:ACUTE: IRRITATION, CENTRAL NERVOUS
    SYSTEM EFFECTS. GASOLINE IF SWALLOWED, MAY BE ASPIRATED INTO LUNGS,
    RESULTING IN PULMONARY EDEMA AND CHEMICAL PNEUMONITIS. CHRONIC:
    BENZENE IS A CONFIRMED CARCINOGEN  AND MAY PRODUCE BLOOD CHANGES.
    PROLONGED EXPOSURE TO HIGH CONCENTRATIONS HAS CAUSED KIDNEY AND
    LIVER CANCER IN RAT/MICE
Explanation of Carcinogenicity:BENZENE IS A CONFIRMED CARCINOGEN BY
    NTP, IARC AND OSHA.
Effects of Overexposure:EYES/SKIN: IRRITATION. INHALATION: COUGHING,
    HEADACHE, DIZZINESS, MENTAL CONFUSION, BLURRED VISION, SLURRED
    SPEECH, WEAKNESS, RESPIRATORY ARREST, CONVULSIONS, COMA. INGESTION:
    IRRITATION OF GASTROINTE STINAL SYSTEM, VOMITING, SAME SYMPTOMS AS
    INHALATION.
Medical Cond Aggravated by Exposure:INDIVIDUALS WITH A HISTORY OF SKIN,
    RESPIRATORY OR CENTRAL NERVOUS SYSTEM DISORDERS MAY BE AT INCREASED
    RISK FROM EXPOSURE.

=======================  First Aid Measures  =======================

First Aid:EYES: FLUSH WITH PLENTY OF WATER FOR 15 MINUTES. SEE DOCTOR.
    SKIN: REMOVE CONTAMINATED CLOTHING AND SHOES. WASH WITH SOAP AND
    WATER. SEE DOCTOR. INHALATION: REMOVE VICTIM TO FRESH AIR. GIVE
    OXYGEN/CPR	IF NEEDED. SEE DOCTOR. IF LIQUID IS INLUNGS
    (ASPIRATED), SEEK MEDICAL CARE. INGESTION: DO NOT INDUCE VOMITING.
    GIVE 1-2 GLASSES OF WATER. SEE DOCTOR IMMEDIATELY.

=====================  Fire Fighting Measures  =====================

Flash Point Method:CC
Flash Point:-45F,-43C
Autoignition Temp:Autoignition Temp Text:830F
Lower Limits:1.4
Upper Limits:7.6
Extinguishing Media:USE CARBON DIOXIDE, FOAM, DRY CHEMICAL, HALON. DO
    NOT USE DIRECT WATER STREAM.
Fire Fighting Procedures:WEAR FIRE FIGHTING PROTECTIVE EQUIPMENT AND A
    FULL FACED SELF CONTAINED BREATHING APPARATUS. COOL FIRE EXPOSED
    CONTAINERS WITH WATER SPRAY.
Unusual Fire/Explosion Hazard:EXTREMELY FLAMMABLE. VAPORS CAN TRAVEL
    ALONG GROUND AND FLASHBACK EXPLOSIVELY. CONTAINERS MAY BURST WITH
    HEAT OF FIRE. COMBUSTION MAY GENERATE TOXIC GASES.

==================  Accidental Release Measures  ==================

Spill Release Procedures:ELIMINATE IGNITION SOURCES. VENTILATE AREA.
    USE NON-SPARKING TOOLS. WEAR PROPER PROTECTIVE EQUIPMENT. STOP LEAK
    AND CONTAIN SPILL. ABSORB IN NON-FLAMMAABLE ABSORBENT AND PLACE IN
    APPROPIATE DISPOSAL C ONTAINER AND SEAL. WASH AREA WITH PLENTY OF
    WATER.

======================	Handling and Storage  ======================

Handling and Storage Precautions:STORE IN COOL, DRY, WELL VENTILATED
    PLACE, AWAY FROM HEAT, IGNITION SOURCES AND INCOMPATIBLE MATERIALS.
    KEEP CONTAINERS CLOSED WHEN NOT IN USE.
Other Precautions:AVOID BREATHING VAPORS, AND EYE AND SKIN CONTACT. USE
    ONLY WITH ADEQUATE VENTILATION. DO NOT SIPHON BY MOUTH. BOND AND
    GROUND CONTAINERS DURING TRANSFER. PROTECT CONTAINERS FROM PHYSICAL
    DAMAGE.

=============  Exposure Controls/Personal Protection  =============

Respiratory Protection:NIOSH/MSHA RESPIRATOR WITH ORGANIC VAPOR
    CARTRIDGE APPROPIATE FOR EXPOSURE OF CONCERN OR SCBA IF TLV IS
    EXCEEDED.
Ventilation:SUFFICIENT MECHANICAL (GENERAL) AND/OR LOCAL EXHAUST
    VENTILATION. USE EXPLOSION-PROOF EQUIPMENT.
Protective Gloves:VITON, NITRILE, PVA.
Eye Protection:SAFETY GLASSES WITH SIDE SHIELDS.
Other Protective Equipment:FULL BODY LONG-SLEEVED GARMENTS TO PREVENT
    REPEATED OR PROLONGED SKIN CONTACT. EYE WASH STATION AND SAFETY
    SHOWER.
Work Hygienic Practices:AVOID CONTACT WITH EYES AND SKIN. DO NOT
    BREATHE VAPORS. WASH THOROUGHLY AFTER HANDLING. LAUNDER
    CONTAMINATED CLOTHING.
Supplemental Safety and Health
THESE PRECAUTIONS ARE FOR NORMAL USES AND CONDITIONS. WHERE SPECIAL OR
    UNUSUAL CONDITIONS EXIST, CONSULT AN INDUSTRIAL HYGIENIST.	RCRA
    CLASSIFICATION IGNITABLE (D001). EP TOXIC (U019).

==================  Physical/Chemical Properties  ==================

HCC:F2
Boiling Pt:B.P. Text:90-440F
Vapor Pres:465-698
Vapor Density:3-4
Spec Gravity:0.7-0.8
Solubility in Water:SLIGHT.
Appearance and Odor:CLEAR LIQUID, AROMATIC ODOR, WITH DISTINCT ETHER
    SMELL.
Percent Volatiles by Volume:100

=================  Stability and Reactivity Data  =================

Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZING AGENTS, HALOGENS, STRONG ACIDS AND ALKALIES.
Stability Condition to Avoid:HIGH HEAT, OPEN FLAMES AND OTHER SOURCES
    OF IGNITION.
Hazardous Decomposition Products:CARBON OXIDES AND VARIOUS HYDROCARBONS
    WHEN BURNED.

====================  Disposal Considerations  ====================

Waste Disposal Methods:CONSULT YOUR LOCAL ENVIRONMENTAL OFFICER.
    DISPOSE OF IN ACCORDANCE WITH ALL APPLICABLE FEDERAL, STATE AND
    LOCAL ENVIRONMENTAL REGULATIONS.

 Disclaimer (provided with this information by the compiling agencies):
 This information is formulated for use by elements of the Department
 of Defense.  The United States of America in no manner whatsoever,
 expressly or implied, warrants this information to be accurate and
 disclaims all liability for its use.  Any person utilizing this
 document should seek competent professional advice to verify and
 assume responsibility for the suitability of this information to their
 particular situation.