CITGO PETROLEUM CORP -- GASOLINES-ALL GRADES UNLEADED, 1600  -- 9140-00N060727
<pre>=====================  Product Identification  =====================

Product ID:GASOLINES-ALL GRADES UNLEADED, 1600
MSDS Date:10/21/1994
FSC:9140
NIIN:00N060727
MSDS Number: BXWZB
=== Responsible Party ===
Company Name:CITGO PETROLEUM CORP
Box:3758
City:TULSA
State:OK
ZIP:74102
Country:US
Info Phone Num:918-495-5933
Emergency Phone Num:800-424-9300(CHEMTREC)
CAGE:1JW40
=== Contractor Identification ===
Company Name:CITGO PETROLEUM CORP
Address:OFF HWY 108
Box:3758
City:LAKE CHARLES
State:LA
ZIP:70602
Country:US
Phone:918-561-5165
CAGE:1JW40
Company Name:CITIES SERVICE CO
Address:110 W 7TH
Box:300
City:TULSA
State:OK
ZIP:74102
Country:US
CAGE:12518

=============  Composition/Information on Ingredients  =============

Ingred Name:PETROLEUM DISTILLATES; (PETROLEUM DISTILLATES MFR CAS
    #:MIXTURE)
Fraction by Wt: 85-98%
OSHA PEL:N/K 
ACGIH TLV:N/K 

Ingred Name:BENZENE (SARA 313) (CERCLA); LD50(ORAL,RAT):>5.0 G/KG
CAS:71-43-2
RTECS #:CY1400000
Fraction by Wt: <5%
OSHA PEL:SEE 1910.1028
ACGIH TLV:10 PPM; A2
EPA Rpt Qty:10 LBS
DOT Rpt Qty:10 LBS

Ingred Name:LOWER ALIPHATIC ALCOHOLS; LD50(ORAL,RAT):>5.0 G/KG
Fraction by Wt: 0-11%
OSHA PEL:N/K 
ACGIH TLV:N/K 

Ingred Name:LOWER ALIPHATIC ETHERS; LD50(ORAL,RAT):4 ML/KG
Fraction by Wt: 0-15%
OSHA PEL:N/K 
ACGIH TLV:N/K 

Ingred Name:TERT-BUTYL ALCOHOL; (TERTIARY BUTYL ALCOHOL) (SARA 313)
CAS:75-65-0
RTECS #:EO1925000
Fraction by Wt: 0-10%
OSHA PEL:100 PPM
ACGIH TLV:100 PPM

Ingred Name:BENZENE ETHYL-; (ETHYL BENZENE) (SARA 313)
CAS:100-41-4
RTECS #:DA0700000
Fraction by Wt: 0-5%
OSHA PEL:100 PPM
ACGIH TLV:100 PPM
EPA Rpt Qty:1000 LBS
DOT Rpt Qty:1000 LBS

Ingred Name:ETHER, TERT-BUTYL METHYL; (METHYL-T-BUTYL ETHER) (SARA 313)
    (CERCLA)
CAS:1634-04-4
RTECS #:KN5250000
Fraction by Wt: 0-15%
OSHA PEL:N/K 
ACGIH TLV:N/K 
EPA Rpt Qty:1 LB
DOT Rpt Qty:1 LB

Ingred Name:TOLUENE (SARA 313) (CERCLA)
CAS:108-88-3
RTECS #:XS5250000
Fraction by Wt: 0-25%
OSHA PEL:200 PPM
ACGIH TLV:S, 50 PPM
EPA Rpt Qty:1000 LBS
DOT Rpt Qty:1000 LBS

Ingred Name:BENZENE, 1,2,4-TRIMETHYL-; (1,2,4-TRIMETHYLBENZENE) (SARA
    313)
CAS:95-63-6
RTECS #:DC3325000
Fraction by Wt: 0-5%
OSHA PEL:25 PPM
ACGIH TLV:25 PPM

Ingred Name:XYLENE; (XYLENE (MIXED ISOMERS)) (SAR
CAS:1330-20-7
RTECS #:ZE2100000
EPA Rpt Qty:1000 LBS
DOT Rpt Qty:1000 LBS

=====================  Hazards Identification  =====================

LD50 LC50 Mixture:SEE INGREDIENTS
Routes of Entry: Inhalation:YES  Skin:YES  Ingestion:NO
Reports of Carcinogenicity:NTP:YES    IARC:YES	  OSHA:YES
Health Hazards Acute and Chronic:ACUTE:INHAL:MOD RISK OF VAP INTOX.
    MAJOR RISK IN ENCLSD SPACES W/POOR VENT:EUPHORIA, LUNG IRRIT &
    EDEMA, HDCH, DIZZ, DROW, CONVLS, COMA, CYANOSIS, GENERALIZED
    DEPRESSION. SKIN:DEFATTING W/DRYING. EYE: IRRIT. INGEST:BURNING OF
    MOUTH & UPPER GI TRACT, VOMIT & DIARR. ABOVE 1 OZ/< 1 OZ
    W/RETENTION:GENERAL (EFTS OF OVEREXP)
Explanation of Carcinogenicity:BENZENE:IARC MONOGRAPHS, SUPP, VOL 7, PG
    20, 1987:GROUP 1. NTP 7TH ANNUAL RPT ON CARCINS, 1994:KNOWN TO BE
    (SUP DATA)
Effects of Overexposure:HLTH HAZS:DEPRESS, SEDATION, RESP DEPRESS,
    COMA. CHRONIC:SKIN:DRYING (DERM). INHAL:BENZENE HAS BEEN CLASSIFIED
    AS LEUKEMOGEN, & MAY PRDCE ANEMIA, LEUKEMIA FROM RPTD/PRLNGD EXPOS
    TO HIGH CONCS. AMERICA N PETROL INSTITUTE SPONSORED CHRONIC INHAL
    STUDIES OF UNLEADED GASOLINE VAPS INDICATING UNLEADED GASOLINE IS
    (ING 12)
Medical Cond Aggravated by Exposure:PRE-EXISTING DERMATOSES.

=======================  First Aid Measures  =======================

First Aid:INHAL:REMOVE TO FRESH AIR. RESP SUPPORT, IF NEC. SEEK MED
    AID. SKIN:WASH W/SOAP & WATER. DO NOT WEAR HEAVILY CONTAM CLTHG
    BEFORE CLEANING. EYES:FLUSH W/LG VOLS OF WATER FOR AT LST 15 MIN.
    SEEK MED AID . INGEST:DO NOT INDUCE VOMIT. SEEK MED AID. NOTE TO
    MD:THIS IS LOW VISCOSITY MATL W/SAYBOLT VISCOSITY @ 100F OF <40
    SUS. PULM HIGH ASPIR HAZ, POSS PRDCING LIPOID PNEUM IF SWALLOWED &
    VOMIT (ING 14)

=====================  Fire Fighting Measures  =====================

Flash Point Method:COC
Flash Point:-45F,-43C
Lower Limits:1.4%
Upper Limits:7.6%
Extinguishing Media:CO*2, DRY CHEMICAL, FOAM, WATER FOG.
Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED SCBA & FULL
    PROTECTIVE EQUIPMENT .
Unusual Fire/Explosion Hazard:MATERIAL IS HIGHLY VOLATILE AND EMITS
    VAPORS WHICH MAY BE IGNITED BY OTHER IGNITION SOURCES.

==================  Accidental Release Measures  ==================

Spill Release Procedures:REMOVE SOURCES OF IGNIT, VENT AREA. SM
    SPILLS:TAKE UP W/NON-COMBUST ABSORB SUCH AS FULLERS EARTH/SAND.
    PLACE INTO CNTNRS FOR LATER DISP. LG SPILL:CNTN IN EARTHEN DIKES
    FOR LATER RECOVERY. CTL IGNIT SO URCES AROUND SPILL AREA.
    FIRE-FIGHTING (ING 15)
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

======================	Handling and Storage  ======================

Handling and Storage Precautions:KEEP CNTNR TIGHTLY CLSD & AWAY FROM
    HEAT & FLAME & STRONG OXIDIZERS (NFPA CLASS 1A FLAM). DO NOT STORE
    W/STRONG OXIDIZERS.
Other Precautions:CAUTN:EMPTY CNTNRS MAY CNTN PROD RESIDUE WHICH COULD
    PRDCE FLAM & EXPLO VAPS. CONSULT APPROP FED, STATE & LOC AUTHS
    BEFORE REUSING, RECNDNTING, RECLAIMING, RECYCLING/DISP OF EMPTY
    CNTNRS &/OR WASTE RE SIDUES OF PROD. PROT MEASURES (ING 22)

=============  Exposure Controls/Personal Protection  =============

Respiratory Protection:IF HIGH VAPOR CONCENTRATION IS EXPECTED, USE
    NIOSH/MSHA APPROVED ORGANIC RESPIRATOR. TLV:TWA: 300 PPM (900
    MG/M3) STEL:500 PPM (1500 MG/M3) ACGIH-1987-88.
Ventilation:USE IN WELL VENT AREA. IN CONFINED SPACE, MECH VENT MAY BE
    REQ TO KEEP LEVELS OF CERTAIN COMPONENTS BELOW (ING 20)
Protective Gloves:OIL IMPERVIOUS GLOVES, SUCH AS (ING 21)
Eye Protection:ANSI APPROVED CHEM WORKERS GOGGS .
Other Protective Equipment:ANSI APPRVD EMER EYE WASH & DELUGE SHOWER .
    WEAR BODY-COVERING GARMENTS TO PVNT PRLNGD/RPTD DIRECT DERM EXPOS.
Work Hygienic Practices:WASH EXPOSED SKIN THORO WITH SOAP AND WATER.
    LAUNDER GASOLINE SOAKED CLOTHING BEFORE REUSE.
Supplemental Safety and Health
BP:>79F,>26C (SUBJECT TO SEASONAL CHANGE). VP:7-15 (MEETS SEASONAL RVP
    REQS SPECIFIED BY EPA). APPEAR & ODOR:LIQ, GASOLINE ODOR.
    MIDGRADE:LIGHT YELLOW, TO PINK, TO LIGHT RED, GASOLINE ODOR. EXPLAN
    OF	CARCIN:CARCIN. FED REGISTER, VOL 52, PG34460, 1987:OSHA-CANCER
    HAZ HUMAN:MYELOID LEUKEMIA, HODGKINS DISEASE, LYMPHOMA.

==================  Physical/Chemical Properties  ==================

Boiling Pt:B.P. Text:SUPP DATA
Vapor Pres:SUPP DATA
Vapor Density:3-4
Spec Gravity:0.75 (H*2O=1)
Evaporation Rate &amp; Reference:>1 (BUTYL ACETATE=1)
Solubility in Water:NEGLIGIBLE
Appearance and Odor:UNLEADED:LIGHT YELLOW OR CLEAR LIQ, GASOLINE ODOR.
    PREMIUM:RED CLEAR (SUPP DATA
Percent Volatiles by Volume:HIGH

=================  Stability and Reactivity Data  =================

Stability Indicator/Materials to Avoid:YES
STRONG OXIDANTS, STRONG ACIDS, CAUSTICS.
Stability Condition to Avoid:HIGH TEMPERATURE, FLAME.
Hazardous Decomposition Products:CO*2, (CO UNDER INCOMPLETE
    COMBUSTION).

====================  Disposal Considerations  ====================

Waste Disposal Methods:DISP MUST BE I/A/W FED, STATE & LOC REGS IT IS
    RESPONSIBILITY OF USER TO DETERM IF MATL IS HAZ WASTE AT TIME OF
    DISP. CHECK BEFORE DISP TO BE SURE YOU ARE IN COMPLIANCE W/ALL
    APPLIC LAWS & REGS.  RCRA EMER HOTLINE #:800-424-9346.

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