CUPRIC SULFATE ANHYDROUS
MSDS Number: C5920 --- Effective Date: 12/08/96
1. Product Identification
Synonyms: Copper (II) sulfate (1:1); copper monosulfate; sulfuric
acid copper (2+) salt (1:1); blue copper
CAS No.: 7758-98-7
Molecular Weight: 159.60
Chemical Formula: CuSO4
Product Codes: J.T. Baker:
1850
Mallinckrodt:
4760, 4800, 4848
2. Composition/Information on Ingredients
Ingredient CAS No Percent Hazardous
--------------------------------------- ------------ ------- ---------
Cupric Sulfate 7758-98-7 100% Yes
3. Hazards Identification
Emergency Overview
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WARNING! HARMFUL IF SWALLOWED. AFFECTS THE LIVER AND KIDNEYS. CAUSES
IRRITATION TO SKIN, EYES AND RESPIRATORY TRACT.
J.T. Baker SAF-T-DATA(tm) Ratings (Provided here for your convenience)
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Health Rating: 2 - Moderate
Flammability Rating: 0 - None
Reactivity Rating: 0 - None
Contact Rating: 2 - Moderate
Lab Protective Equip: GOGGLES; LAB COAT; VENT HOOD; PROPER GLOVES
Storage Color Code: Orange (General Storage)
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Potential Health Effects
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Inhalation:
Causes irritation to respiratory tract, symptoms may include coughing, sore
throat, and shortness of breath. May result in ulceration and perforation
of respiratory tract. When heated, this compound may give off copper fume,
which can cause symptoms similar to the common cold, including chills and
stuffiness of the head.
Ingestion:
May cause burning pain in the mouth, esophagus, and stomach. Hemorrhagic
gastritis, nausea, vomiting, abdominal pain, metallic taste, and diarrhea
may occur. If vomiting does not occur immediately systemic copper poisoning
may occur. Symptoms may include capillary damage, headache, cold sweat,
weak pulse, kidney and liver damage, central nervous excitation followed by
depression, jaundice, convulsions, blood effects, paralysis and coma. Death
may occur from shock or renal failure. Fatalities have occurred as a result
of ingesting gram quantities of copper sulfate.
Skin Contact:
May cause irritation, itching, redness. Contact with extensively burned
skin may cause poisoning.
Eye Contact:
Dust may cause irritation. Contact may cause conjunctivitis, ulceration, or
clouding of the cornea.
Chronic Exposure:
Prolonged or repeated skin exposure may cause dermatitis. Prolonged or
repeated exposure to dusts of copper salts may cause discoloration of the
skin or hair, blood and liver damage, ulceration and perforation of the
nasal septum, runny nose, metallic taste, and atrophic changes and
irritation of the mucous membranes.
Aggravation of Pre-existing Conditions:
Persons with pre-existing skin disorders, impaired liver, kidney, or
pulmonary function, glucose 6-phosphate-dehydrogenase deficiency, or
pre-existing Wilson's disease may be more susceptible to the effects of
this material.
4. First Aid Measures
Inhalation:
Remove to fresh air. If not breathing, give artificial respiration. If
breathing is difficult, give oxygen. Call a physician.
Ingestion:
Induce vomiting immediately as directed by medical personnel. Never give
anything by mouth to an unconscious person. Call a physician immediately.
Skin Contact:
In case of contact, wipe off excess material from skin then immediately
flush skin with plenty of water for at least 15 minutes. Remove
contaminated clothing and shoes. Wash clothing before reuse. Call a
physician.
Eye Contact:
Immediately flush eyes with plenty of water for at least 15 minutes,
lifting lower and upper eyelids occasionally. Get medical attention
immediately.
5. Fire Fighting Measures
Fire:
Not considered to be a fire hazard.
Explosion:
Not considered to be an explosion hazard.
Fire Extinguishing Media:
Use any means suitable for extinguishing surrounding fire. Water spray may
be used to keep fire exposed containers cool.
Special Information:
In the event of a fire, wear full protective clothing and NIOSH-approved
self-contained breathing apparatus with full facepiece operated in the
pressure demand or other positive pressure mode. When heated above 110C
(230F) material will melt. Avoid using a direct water stream on molten
material as it may causes splattering.
6. Accidental Release Measures
Ventilate area of leak or spill. Keep unnecessary and unprotected people
away from area of spill. Wear appropriate personal protective equipment as
specified in Section 8. Spills: Pick up and place in a suitable container
for reclamation or disposal, using a method that does not generate dust. US
Regulations (CERCLA) require reporting spills and releases to soil, water
and air in excess of reportable quantities. The toll free number for the US
Coast Guard National Response Center is (800) 424-8802.
7. Handling and Storage
Keep in a tightly closed container, stored in a cool, dry, ventilated area.
Protect against physical damage. Isolate from incompatible substances.
Containers of this material may be hazardous when empty since they retain
product residues (dust, solids); observe all warnings and precautions
listed for the product.
8. Exposure Controls/Personal Protection
Airborne Exposure Limits:
-OSHA Permissible Exposure Limit (PEL):
1 mg/m3 (TWA) for copper dusts & mists as Cu
-ACGIH Threshold Limit Value (TLV):
1 mg/m3 (TWA) for copper dusts & mists as Cu
Ventilation System:
A system of local and/or general exhaust is recommended to keep employee
exposures below the Airborne
Exposure Limits. Local exhaust ventilation is generally preferred because
it can control the emissions of the contaminant at its source, preventing
dispersion of it into the general work area. Please refer to the ACGIH
document, Industrial Ventilation, A Manual of Recommended Practices,
most recent edition, for details.
Personal Respirators (NIOSH Approved):
If the exposure limit is exceeded, a half-face dust/mist respirator may be
worn for up to ten times the exposure limit or the maximum use
concentration specified by the appropriate regulatory agency or respirator
supplier, whichever is lowest. A full-face piece dust/mist respirator may
be worn up to 50 times the exposure limit, or the maximum use concentration
specified by the appropriate regulatory agency, or respirator supplier,
whichever is lowest. For emergencies or instances where the exposure
levels are not known, use a full-facepiece positive-pressure, air-supplied
respirator. WARNING: Air-purifying respirators do not protect workers in
oxygen-deficient atmospheres.
Skin Protection:
Wear protective gloves and clean body-covering clothing.
Eye Protection:
Use chemical safety goggles. Maintain eye wash fountain and quick-drench
facilities in work area.
9. Physical and Chemical Properties
Appearance:
Grayish-white to greenish-white rhombic crystals.
Odor:
Odorless.
Solubility:
14.3% in water @ 0C (32F)
Specific Gravity:
3.60
pH:
No information found.
% Volatiles by volume @ 21C (70F):
0
Boiling Point:
650C (1202F)
Melting Point:
> 200C (> 392F) Slowly decomposes
Vapor Density (Air=1):
No information found.
Vapor Pressure (mm Hg):
No information found.
Evaporation Rate (BuAc=1):
No information found.
10. Stability and Reactivity
Stability:
Stable under ordinary conditions of use and storage. Hygroscopic.
Hazardous Decomposition Products:
Burning may produce sulfur oxides.
Hazardous Polymerization:
Will not occur.
Incompatibilities:
Substance will ignite hydroxylamine. Solutions are acidic and can react
with magnesium to evolve flammable hydrogen gas. May react with acetylene
to form dangerous acetylides.
Conditions to Avoid:
Moisture and incompatibles.
11. Toxicological Information
Toxicological Data:
Oral rat LD 50: 300 mg/kg. Investigated as a tumorigen, mutagen and
reproductive effector.
Reproductive Toxicity:
Has caused mutagenic and teratogenic effects on laboratory animals.
--------\Cancer Lists\------------------------------------------------------
---NTP Carcinogen---
Ingredient Known Anticipated IARC Category
------------------------------------ ----- ----------- -------------
Cupric Sulfate (7758-98-7) No No None
12. Ecological Information
Environmental Fate:
When released into the soil, this material is not expected to biodegrade.
When released into the soil, this material may leach into groundwater. When
released into water, this material is not expected to biodegrade. When
released into water, this material is not expected to evaporate
significantly. This material is expected to significantly bioaccumulate.
This material has an experimentally-determined bioconcentration factor
(BCF) of greater than 100. Bioaccumulation data for copper.
Environmental Toxicity:
Toxicity data for copper. This material is expected to be very toxic to
aquatic life. The LC50/96-hour values for fish are less than 1 mg/l. The
IC50/72-hour values for algae are less than 1 mg/l.
13. Disposal Considerations
Whatever cannot be saved for recovery or recycling should be managed in an
appropriate and approved waste disposal facility. Processing, use or
contamination of this product may change the waste management options.
State and local disposal regulations may differ from federal disposal
regulations.
Dispose of container and unused contents in accordance with federal, state
and local requirements.
14. Transport Information
Domestic (Land, D.O.T.)
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Proper Shipping Name: RQ, ENVIRONMENTALLY HAZARDOUS SUBSTANCES, SOLID,
N.O.S. (CUPRIC SULFATE)
Hazard Class: 9
UN/NA: UN3077
Packing Group: III
Information reported for product/size: 100LB
15. Regulatory Information
--------\Chemical Inventory Status - Part 1\---------------------------------
Ingredient TSCA EC Japan Australia
----------------------------------------------- ---- --- ----- ---------
Cupric Sulfate (7758-98-7) Yes Yes Yes Yes
--------\Chemical Inventory Status - Part 2\---------------------------------
--Canada--
Ingredient Korea DSL NDSL Phil.
----------------------------------------------- ----- --- ---- -----
Cupric Sulfate (7758-98-7) Yes Yes No Yes
--------\Federal, State & International Regulations - Part 1\----------------
-SARA 302- ------SARA 313------
Ingredient RQ TPQ List Chemical Catg.
----------------------------------------- --- ----- ---- --------------
Cupric Sulfate (7758-98-7) No No No Copper compo
--------\Federal, State & International Regulations - Part 2\----------------
-RCRA- -TSCA-
Ingredient CERCLA 261.33 8(d)
----------------------------------------- ------ ------ ------
Cupric Sulfate (7758-98-7) 10 No No
Chemical Weapons Convention: No TSCA 12(b): No CDTA: No
SARA 311/312: Acute: Yes Chronic: Yes Fire: No Pressure: No
Reactivity: No (Pure / Solid)
Australian Hazchem Code: No information found.
Poison Schedule: S5
WHMIS:
This MSDS has been prepared according to the hazard criteria of
the Controlled Products Regulations (CPR) and the MSDS contains
all of the information required by the CPR.
16. Other Information
NFPA Ratings:
Health: 2 Flammability: 0 Reactivity: 0
Label Hazard Warning:
WARNING! HARMFUL IF SWALLOWED. AFFECTS THE LIVER AND KIDNEYS. CAUSES
IRRITATION TO SKIN, EYES AND RESPIRATORY TRACT.
Label Precautions:
Avoid contact with eyes, skin and clothing.
Wash thoroughly after handling.
Keep container closed.
Avoid breathing dust.
Use only with adequate ventilation.
Label First Aid:
If swallowed, induce vomiting immediately as directed by medical personnel.
Never give anything by mouth to an unconscious person. Call a physician
immediately. In case of contact, wipe off excess material from skin then
immediately flush eyes or skin with plenty of water for at least 15 minutes.
Remove contaminated clothing and shoes. Wash clothing before reuse. Call a
physician. If inhaled, remove to fresh air. If not breathing, give artificial
respiration. If breathing is difficult, give oxygen. Call a physician.
Product Use:
Laboratory Reagent.
Revision Information:
Pure. New 16 section MSDS format, all sections have been revised.
Disclaimer:
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Mallinckrodt Baker, Inc. provides the information contained herein in good
faith but makes no representation as to its comprehensiveness or accuracy. This
document is intended only as a guide to the appropriate precautionary handling
of the material by a properly trained person using this product. Individuals
receiving the information must exercise their independent judgment in
determining its appropriateness for a particular purpose. MALLINCKRODT BAKER,
INC. MAKES NO REPRESENTATIONS OR WARRANTIES, EITHER EXPRESS OR IMPLIED,
INCLUDING WITHOUT LIMITATION ANY WARRANTIES OF MERCHANTABILITY, FITNESS FOR A
PARTICULAR PURPOSE WITH RESPECT TO THE INFORMATION SET FORTH HEREIN OR THE
PRODUCT TO WHICH THE INFORMATION REFERS. ACCORDINGLY, MALLINCKRODT BAKER, INC.
WILL NOT BE RESPONSIBLE FOR DAMAGES RESULTING FROM USE OF OR RELIANCE UPON THIS
INFORMATION.
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Prepared by: Strategic Services Division
Phone Number: (314) 539-1600 (U.S.A.)